MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction
文献类型:期刊论文
作者 | Wang, Fei; Ta, Na; Shen, Wenjie |
刊名 | applied catalysis a-general
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出版日期 | 2014-04-05 |
卷号 | 475页码:76-81 |
关键词 | MgO Morphology Nanosheets Nanodisks Nanofibers Basic sites |
英文摘要 | mgo nanosheets, nanodisks, and nanofibers were synthesized by a hydrothermal method with the aid of suitable surfactants. the nanosheets and nanodisks exposed the (1 1 1) facets mainly whereas the nanofibers exposed a mixture of the (1 1 1), (1 0 0), and (1 1 0) planes. the total number and the surface density of the basic sites followed the order nanosheets > nanodisks > nanofibers. when being used to catalyze the meerwein-ponndorf-verley reaction between benzaldehyde and ethanol, the nanosheets and nanodisks showed much higher reaction rates than the nanofibers, primarily because of their large numbers of surface basic sites that might be linked to the preferential exposure of the {1 1 1} facets. (c) 2014 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
类目[WOS] | chemistry, physical ; environmental sciences |
研究领域[WOS] | chemistry ; environmental sciences & ecology |
关键词[WOS] | unsaturated aldehydes ; mgo(111) nanosheets ; biodiesel synthesis ; hydrogen-transfer ; magnesium-oxide ; reduction ; catalysts ; surface ; 2-propanol ; ethanol |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000335610400010 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/143217] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Fei,Ta, Na,Shen, Wenjie. MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction[J]. applied catalysis a-general,2014,475:76-81. |
APA | Wang, Fei,Ta, Na,&Shen, Wenjie.(2014).MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction.applied catalysis a-general,475,76-81. |
MLA | Wang, Fei,et al."MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction".applied catalysis a-general 475(2014):76-81. |
入库方式: OAI收割
来源:大连化学物理研究所
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