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Chinese Academy of Sciences Institutional Repositories Grid
MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction

文献类型:期刊论文

作者Wang, Fei; Ta, Na; Shen, Wenjie
刊名applied catalysis a-general
出版日期2014-04-05
卷号475页码:76-81
关键词MgO Morphology Nanosheets Nanodisks Nanofibers Basic sites
英文摘要mgo nanosheets, nanodisks, and nanofibers were synthesized by a hydrothermal method with the aid of suitable surfactants. the nanosheets and nanodisks exposed the (1 1 1) facets mainly whereas the nanofibers exposed a mixture of the (1 1 1), (1 0 0), and (1 1 0) planes. the total number and the surface density of the basic sites followed the order nanosheets > nanodisks > nanofibers. when being used to catalyze the meerwein-ponndorf-verley reaction between benzaldehyde and ethanol, the nanosheets and nanodisks showed much higher reaction rates than the nanofibers, primarily because of their large numbers of surface basic sites that might be linked to the preferential exposure of the {1 1 1} facets. (c) 2014 elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences ; life sciences & biomedicine
类目[WOS]chemistry, physical ; environmental sciences
研究领域[WOS]chemistry ; environmental sciences & ecology
关键词[WOS]unsaturated aldehydes ; mgo(111) nanosheets ; biodiesel synthesis ; hydrogen-transfer ; magnesium-oxide ; reduction ; catalysts ; surface ; 2-propanol ; ethanol
收录类别SCI
语种英语
WOS记录号WOS:000335610400010
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/143217]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Wang, Fei,Ta, Na,Shen, Wenjie. MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction[J]. applied catalysis a-general,2014,475:76-81.
APA Wang, Fei,Ta, Na,&Shen, Wenjie.(2014).MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction.applied catalysis a-general,475,76-81.
MLA Wang, Fei,et al."MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction".applied catalysis a-general 475(2014):76-81.

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来源:大连化学物理研究所

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