Nitrogen doped carbon catalyzing acetylene conversion to vinyl chloride
文献类型：期刊论文
| 作者 | Li, Xingyun; Pan, Xiulian; Bao, Xinhe |
| 刊名 | journal of energy chemistry
 |
| 出版日期 | 2014-03-01 |
| 卷号 | 23期号:2页码:131-135 |
| 关键词 | acetylene hydrochlorination vinyl chloride mercury-free N doped carbon |
| 英文摘要 | commercial production of vinyl chloride from acetylene relies on the use of hgcl2 as the catalyst, which has caused severe environmental problem and threats to human health because of its toxicity. therefore, it is vital to explore alternative catalysts without mercury. we report here that n-doped carbon can catalyze directly transformation of acetylene to vinyl chloride. particularly, n-doped high surface area mesoporous carbon exhibits a rather high activity with the acetylene conversion reaching 77% and vinyl chloride selectivity above 98% at a space velocity of 1.0 ml.min(-1).g(-1) and 200 degrees c. it delivers a stable performance within a test period of 100 h and no obvious deactivation is observed, demonstrating potentials to substitute the notoriously toxic mercuric chloride catalyst. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; energy & fuels ; engineering, chemical |
| 研究领域[WOS] | chemistry ; energy & fuels ; engineering |
| 关键词[WOS] | ordered mesoporous carbons ; hydrochlorination ; catalysts ; reactivation ; regeneration |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000334145500001 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/143222]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xingyun,Pan, Xiulian,Bao, Xinhe. Nitrogen doped carbon catalyzing acetylene conversion to vinyl chloride[J]. journal of energy chemistry,2014,23(2):131-135. |
| APA | Li, Xingyun,Pan, Xiulian,&Bao, Xinhe.(2014).Nitrogen doped carbon catalyzing acetylene conversion to vinyl chloride.journal of energy chemistry,23(2),131-135. |
| MLA | Li, Xingyun,et al."Nitrogen doped carbon catalyzing acetylene conversion to vinyl chloride".journal of energy chemistry 23.2(2014):131-135. |
入库方式： OAI收割
来源：大连化学物理研究所
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