Novel trinuclear copper(II) complexes with alpha,beta-unsaturated carboxylates and imidazole
文献类型：期刊论文
| 作者 | Wang, YY; Zhou, LJ; Shi, Q; Shi, QZ; Gao, YC; Hou, X |
| 刊名 | transition metal chemistry
 |
| 出版日期 | 2002-03-01 |
| 卷号 | 27期号:2页码:145-148 |
| 英文摘要 | a meoh solution of imidazole reacts with cu(2)a(4)(h2o)(2) [a = ch2=chco2-, ch2=c(me)co2-] to yield novel trinuclear copper(ii) carboxylate complexes of general formula: cu(3)a(5)(oh)(imh)(3) [(1) a=ch2=chco2-; (2) a = ch2=c(me)co2-; imh = imidazole]. the crystal structure of (2) has been determined. the geometry of one copper(ii) atom is distorted trigonal bipyramidal, and the other two copper(ii) atoms are distorted square-planar. the i.r. spectra show the presence of the absorption bands of both bidentate mu(2)-o,o' and monodentate carboxylate ligands. the electronic reflectance spectra in the solid state suggest that the d-d transitions of complexes are in a trigonal bipyramidal ligand field and a square-planar ligand field. room temperature x-band e.s.r. spectra of powdered samples with g(av) = 2.140 for (1) and g(av) = 2.092 for (2), indicate that there is no spin coupling between the copper(ii) atoms. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, inorganic & nuclear |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | crystal-structure ; comparative crystallography ; electronic-properties ; magnetic-properties ; molecular-structure ; pathways ; 1,10-phenanthroline ; ligands ; sites |
| 收录类别 | SCI ; EI |
| 语种 | 英语 |
| WOS记录号 | WOS:000173585900003 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://ir.opt.ac.cn/handle/181661/25449]  |
| 专题 | 西安光学精密机械研究所_中国科学院西安光学精密机械研究所(2010年前) |
| 作者单位 | 1.NW Univ Xian, Dept Chem, Xian 710069, Peoples R China 2.Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Xian Inst Opt & Precis Mech, Xian 710069, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, YY,Zhou, LJ,Shi, Q,et al. Novel trinuclear copper(II) complexes with alpha,beta-unsaturated carboxylates and imidazole[J]. transition metal chemistry,2002,27(2):145-148. |
| APA | Wang, YY,Zhou, LJ,Shi, Q,Shi, QZ,Gao, YC,&Hou, X.(2002).Novel trinuclear copper(II) complexes with alpha,beta-unsaturated carboxylates and imidazole.transition metal chemistry,27(2),145-148. |
| MLA | Wang, YY,et al."Novel trinuclear copper(II) complexes with alpha,beta-unsaturated carboxylates and imidazole".transition metal chemistry 27.2(2002):145-148. |
入库方式： OAI收割
来源：西安光学精密机械研究所
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