Direct imaging of the Fermi resonance interaction in para-difluorobenzene: A special insight into energy redistributions in the S-1 low-energy regime
文献类型：期刊论文
| 作者 | Long, Jinyou; Qin, Chaochao; Liu, Yuzhu; Zhang, Song; Zhang, Bing1 |
| 刊名 | PHYSICAL REVIEW A
 |
| 出版日期 | 2011-12-07 |
| 卷号 | 84期号:6 |
| 英文摘要 | We have experimentally observed the dynamics of the Fermi resonance interaction in the S-1 low-energy regime of para-difluorobenzene at +819 cm(-1) by femtosecond time-resolved photoelectron imaging technique. The Fermi resonance interaction is clearly demonstrated by the time dependence of the photoelectron spectra; furthermore, the corresponding photoelectron angular distributions (PADs) clearly reflect each Fermi component character of the resonance 5(1) . . . 6(2). The oscillation period for the Fermi resonance is estimated to be less than 20 ps from the time behavior of the photoelectron spectra, which is very close to our calculated oscillation period value of 13.3 ps. Our results demonstrate the vibrational energy transfer between the two Fermi resonance components of 5(1) and 6(2), suggestive of a special insight into the vibrational energy redistribution in the S-1 low-energy regime of para-difluorobenzene. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Optics ; Physics, Atomic, Molecular & Chemical |
| 研究领域[WOS] | Optics ; Physics |
| 关键词[WOS] | INTRAMOLECULAR VIBRATIONAL REDISTRIBUTION ; ULTRAFAST INTERNAL-CONVERSION ; FLUORESCENCE-SPECTRA ; P-DIFLUOROBENZENE ; DYNAMICS ; VAPOR ; STATE ; EXPANSION ; MOTION ; MAP |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000297760000004 |
| 公开日期 | 2015-12-01 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8215]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Long, Jinyou,Qin, Chaochao,Liu, Yuzhu,et al. Direct imaging of the Fermi resonance interaction in para-difluorobenzene: A special insight into energy redistributions in the S-1 low-energy regime[J]. PHYSICAL REVIEW A,2011,84(6). |
| APA | Long, Jinyou,Qin, Chaochao,Liu, Yuzhu,Zhang, Song,&Zhang, Bing.(2011).Direct imaging of the Fermi resonance interaction in para-difluorobenzene: A special insight into energy redistributions in the S-1 low-energy regime.PHYSICAL REVIEW A,84(6). |
| MLA | Long, Jinyou,et al."Direct imaging of the Fermi resonance interaction in para-difluorobenzene: A special insight into energy redistributions in the S-1 low-energy regime".PHYSICAL REVIEW A 84.6(2011). |
入库方式： OAI收割
来源：武汉物理与数学研究所
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