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Acid properties of solid acid catalysts characterized by solid-state P-31 NMR of adsorbed phosphorous probe molecules
文献类型：期刊论文
| 作者 | Zheng, Anmin2; Huang, Shing-Jong3; Liu, Shang-Bin1,4; Deng, Feng2 |
| 刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
 |
| 出版日期 | 2011 |
| 卷号 | 13期号:33页码:14889-14901 |
| 英文摘要 | A brief review is presented on acidity characterization of solid acid catalysts by means of solid-state phosphor-31 magic-angle-spinning nuclear magnetic resonance (P-31 MAS NMR) spectroscopy using phosphor-containing molecules as probes. It is emphasized that such a simple approach using P-31 MAS NMR of adsorbed phosphorous probe molecules, namely trimethylphosphine (TMP) and trialkylphosphine oxides (R3PO), represents a unique technique in providing detailed qualitative and quantitative features, viz. type, strength, distribution, and concentration of acid sites in solid acid catalysts. In particular, it will be shown that when applied with a proper choice of probe molecules with varied sizes and results obtained from elemental analysis, the amounts and locations (intracrystalline vs. extracrystalline) of different types (Bronsted vs. Lewis) of acid sites may be determined. In addition, by incorporating the NMR results with that obtained from theoretical density functional theory (DFT) calculations, correlations between the P-31 chemical shifts (delta P-31) and acidic strengths of Bronsted and Lewis acid sites may also be derived, facilitating a suitable acidity scale for solid acid catalysts. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
| 研究领域[WOS] | Chemistry ; Physics |
| 关键词[WOS] | NUCLEAR-MAGNETIC-RESONANCE ; GOLDBURG CROSS-POLARIZATION ; DEALUMINATED HY ZEOLITE ; TRIMETHYLPHOSPHINE OXIDE ; THEORETICAL CALCULATION ; MAS NMR ; H-ZSM-5 ZEOLITE ; CHEMICAL-SHIFT ; MAGIC-ANGLE ; HIGH-FIELD |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000293860500007 |
| 公开日期 | 2015-12-01 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8223]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan 2.Chinese Acad Sci, Wuhan Ctr Magnet Resonance, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 3.Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan 4.Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan |
| 推荐引用方式 GB/T 7714 | Zheng, Anmin,Huang, Shing-Jong,Liu, Shang-Bin,et al. Acid properties of solid acid catalysts characterized by solid-state P-31 NMR of adsorbed phosphorous probe molecules[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2011,13(33):14889-14901. |
| APA | Zheng, Anmin,Huang, Shing-Jong,Liu, Shang-Bin,&Deng, Feng.(2011).Acid properties of solid acid catalysts characterized by solid-state P-31 NMR of adsorbed phosphorous probe molecules.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,13(33),14889-14901. |
| MLA | Zheng, Anmin,et al."Acid properties of solid acid catalysts characterized by solid-state P-31 NMR of adsorbed phosphorous probe molecules".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 13.33(2011):14889-14901. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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