Measurement of C-13-H-1 dipolar couplings in solids by using ultra-fast magic-angle spinning NMR spectroscopy with symmetry-based sequences
文献类型：期刊论文
| 作者 | Wang, Qiang1,4; Lu, Xingyu1; Lafon, Olivier1; Trebosc, Julien1; Deng, Feng4; Hu, Bingwen2,3; Chen, Qun2,3; Amoureux, Jean-Paul1 |
| 刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
 |
| 出版日期 | 2011 |
| 卷号 | 13期号:13页码:5967-5973 |
| 英文摘要 | We show that C-13-H-1 dipolar couplings in fully protonated organic solids can be measured by applying a Symmetry-based Resonance-Echo DOuble-Resonance (S-REDOR) experiment at ultra-fast Magic-Angle Spinning (MAS). The C-13-H-1 dipolar couplings are recovered by using the R12(3)(5) recoupling scheme, while the interference of H-1-H-1 dipolar couplings are suppressed by the symmetry properties of this sequence and the use of high MAS frequency (65 kHz). The R12(3)(5) method is especially advantageous for large C-13-H-1 dipolar interactions, since the dipolar recoupling time can be incremented by steps as short as one rotor period. This allows a fine sampling for the rising part of the dipolar dephasing curve. We demonstrate experimentally that one-bond C-13-H-1 dipolar coupling in the order of 22 kHz can be accurately determined. Furthermore, the proposed method allows a rapid evaluation of the dipolar coupling by fitting the S-REDOR dipolar dephasing curve with an analytical expression. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
| 研究领域[WOS] | Chemistry ; Physics |
| 关键词[WOS] | ECHO DOUBLE-RESONANCE ; NUCLEAR-MAGNETIC-RESONANCE ; STATE NMR ; FAST-MAS ; DISTANCE MEASUREMENTS ; QUADRUPOLAR NUCLEI ; REDOR ; RESOLUTION ; SIMULATION ; PEPTIDES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000288447100057 |
| 公开日期 | 2015-12-01 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8234]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Lille N France Univ, Unit Catalysis & Chem Solids, CNRS 8181, F-59652 Villeneuve Dascq, France 2.E China Normal Univ, Dept Phys, Shanghai 200062, Peoples R China 3.E China Normal Univ, Shanghai Key Lab Magnet Resonance, Shanghai 200062, Peoples R China 4.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan Ctr Magnet Resonance, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Qiang,Lu, Xingyu,Lafon, Olivier,et al. Measurement of C-13-H-1 dipolar couplings in solids by using ultra-fast magic-angle spinning NMR spectroscopy with symmetry-based sequences[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2011,13(13):5967-5973. |
| APA | Wang, Qiang.,Lu, Xingyu.,Lafon, Olivier.,Trebosc, Julien.,Deng, Feng.,...&Amoureux, Jean-Paul.(2011).Measurement of C-13-H-1 dipolar couplings in solids by using ultra-fast magic-angle spinning NMR spectroscopy with symmetry-based sequences.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,13(13),5967-5973. |
| MLA | Wang, Qiang,et al."Measurement of C-13-H-1 dipolar couplings in solids by using ultra-fast magic-angle spinning NMR spectroscopy with symmetry-based sequences".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 13.13(2011):5967-5973. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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