Synthesis, mechanism and magnetic resonance of new lanthanide complexes with noncyclic polyether - Acetylacetone Schiff base
文献类型：期刊论文
| 作者 | Yao, KM; Wu, J; Chen, DY; Shen, LF; Yuan, HZ |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 1998 |
| 卷号 | 56期号:9页码:900-904 |
| 关键词 | lanthanide complex noncyclic polyether Schiff base beta-diketone enamic form |
| 英文摘要 | Nine novel Ln(III) complexes with Schiff base(ACACDA) derived from diethylene glycol diamine and acetylacetone have been synthesized by the "step by step" method for the first time. They can be formulated as: [Ln(ACACDA)(2)(NO3)(2)(NO3)](NO3)(2). 4H(2)O(Ln = La, Pr, Nd, Sm, Gd, Tb, Er, Yb, Y). Enamic form mechanism in the ligand of the complexes was suggested and proved by UV, IR, especially H-1 and C-13 NMR spectra. The EPR spectrum of the Gd(III) complex exhibits the "U" spectral feature and "zero field effect". On this basis, the crystal field strength and the local symmetry around Gd3+ in the complex have been discussed. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | GADOLINIUM COMPLEXES ; SPECTRA |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000076266300011 |
| 公开日期 | 2015-12-01 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8281]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao, KM,Wu, J,Chen, DY,et al. Synthesis, mechanism and magnetic resonance of new lanthanide complexes with noncyclic polyether - Acetylacetone Schiff base[J]. ACTA CHIMICA SINICA,1998,56(9):900-904. |
| APA | Yao, KM,Wu, J,Chen, DY,Shen, LF,&Yuan, HZ.(1998).Synthesis, mechanism and magnetic resonance of new lanthanide complexes with noncyclic polyether - Acetylacetone Schiff base.ACTA CHIMICA SINICA,56(9),900-904. |
| MLA | Yao, KM,et al."Synthesis, mechanism and magnetic resonance of new lanthanide complexes with noncyclic polyether - Acetylacetone Schiff base".ACTA CHIMICA SINICA 56.9(1998):900-904. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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