Synthesis and characterization of poly(isoprene-b-butyl methacrylate) block copolymer in the presence of rare earth catalyst
文献类型:期刊论文
| 作者 | Zhang, YF; Zheng, RH; Shen, ZQ; Yao, KM; Shen, LF; Yan, HZ; Keim, W |
| 刊名 | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
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| 出版日期 | 1998-08-01 |
| 卷号 | 14期号:3页码:330-334 |
| 关键词 | block copolymerization isoprene butyl methacrylate rare earth catalyst |
| 英文摘要 | Poly (isoprene-b-butyl methacrylate) block copolymer with a high molecular weight was synthesized in the presence of rare earth coordination catalyst [RE(P-204)(3)-Al(i-Bu)(3)-DBE]. The block copolymer was characterized by means of GPC,IR,DSC,NMR and elemental analysis. The block copolymer prepared has two glass transition temperatures: -75.6 degrees C and 32.2 degrees C. The microstructure of the diblock copolymer possessed 96.8% cis-1,4 addition for the isoprene segment and a 70% syndiotacticity for the butyl methacrylate segment. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | METHYL-METHACRYLATE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000075803900022 |
| 公开日期 | 2015-12-01 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8285] ![]() |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表(包括2011年) |
| 作者单位 | 1.Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Peoples R China 2.Acad Sinica, Wuhan Inst Phys, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 3.RWTH, Inst Chem Tech, Aachen, Germany |
| 推荐引用方式 GB/T 7714 | Zhang, YF,Zheng, RH,Shen, ZQ,et al. Synthesis and characterization of poly(isoprene-b-butyl methacrylate) block copolymer in the presence of rare earth catalyst[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,1998,14(3):330-334. |
| APA | Zhang, YF.,Zheng, RH.,Shen, ZQ.,Yao, KM.,Shen, LF.,...&Keim, W.(1998).Synthesis and characterization of poly(isoprene-b-butyl methacrylate) block copolymer in the presence of rare earth catalyst.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,14(3),330-334. |
| MLA | Zhang, YF,et al."Synthesis and characterization of poly(isoprene-b-butyl methacrylate) block copolymer in the presence of rare earth catalyst".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 14.3(1998):330-334. |
入库方式: OAI收割
来源:武汉物理与数学研究所
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