2D CP/MAS C-13 isotropic chemical shift correlation established by H-1 spin diffusion
文献类型：期刊论文
| 作者 | Wilhelm, M; Feng, H; Tracht, U; Spiess, HW |
| 刊名 | JOURNAL OF MAGNETIC RESONANCE
 |
| 出版日期 | 1998-10-01 |
| 卷号 | 134期号:2页码:255-260 |
| 关键词 | 2D C-13 CP/MAS NMR H-1 spin diffusion heterogeneity spatial correlation |
| 英文摘要 | A new 2D solid-state CP/MAS C-13 NMR exchange experiment for through-space isotropic chemical shift correlation is proposed and demonstrated. Through-space correlation is established via a second cross polarization from C-13 to H-1 and subsequent H-1 spin diffusion. A third cross polarization results in the final C-13-C-13 isotropic chemical shift correlation. The H-1 spin diffusion time is a variable parameter allowing different mean square magnetization displacements to be probed. Experimental results on mixtures of differently C-13-labeled alanine and polyethylene indicate that this site-selective 2D technique can be used to characterize domain sizes and proximities over a wide range of length scales (1-200 nm) in solids such as polymers or biological materials. (C) 1998 Academic Press. |
| WOS标题词 | Science & Technology ; Life Sciences & Biomedicine ; Physical Sciences ; Technology |
| 类目[WOS] | Biochemical Research Methods ; Physics, Atomic, Molecular & Chemical ; Spectroscopy |
| 研究领域[WOS] | Biochemistry & Molecular Biology ; Physics ; Spectroscopy |
| 关键词[WOS] | SOLID-STATE NMR ; POLYMER BLENDS ; SPECTROSCOPY ; EXCHANGE |
| 收录类别 | ISTP ; SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000076635800008 |
| 公开日期 | 2015-12-01 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8300]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Max Planck Inst Polymerforsch, D-55021 Mainz, Germany 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wilhelm, M,Feng, H,Tracht, U,et al. 2D CP/MAS C-13 isotropic chemical shift correlation established by H-1 spin diffusion[J]. JOURNAL OF MAGNETIC RESONANCE,1998,134(2):255-260. |
| APA | Wilhelm, M,Feng, H,Tracht, U,&Spiess, HW.(1998).2D CP/MAS C-13 isotropic chemical shift correlation established by H-1 spin diffusion.JOURNAL OF MAGNETIC RESONANCE,134(2),255-260. |
| MLA | Wilhelm, M,et al."2D CP/MAS C-13 isotropic chemical shift correlation established by H-1 spin diffusion".JOURNAL OF MAGNETIC RESONANCE 134.2(1998):255-260. |
入库方式： OAI收割
来源：武汉物理与数学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。