Solid state NMR study of some substituted silatrane compounds
文献类型:期刊论文
作者 | Zhang, XD; Zheng, G; Shen, LF; Ye, CH; Lu, ZR; Zhuo, RX |
刊名 | ACTA CHIMICA SINICA
![]() |
出版日期 | 1998 |
卷号 | 56期号:10页码:986-989 |
关键词 | solid state NMR silatrane molecular structure |
英文摘要 | Solid state NMR technique has been applied in the study of three synthesized silatranyl carboxylic acid compounds. The C-13, Si-29 and N-15 NMR chemical shifts of the compounds are obtained. The experimental results show that in the solid state the silatrane structures are distorted when there is a non-axial carboxyl substituent. In such cases, the strength of the N-Si dative bond is not normally reflected by the behavior of Si-29 and N-15 chemical shifts, and no hydrogen bond or salt is formed in the molecule. The experimental results and discussion are presented in detail. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Multidisciplinary |
研究领域[WOS] | Chemistry |
关键词[WOS] | TRANSANNULAR INTERACTION ; AB-INITIO ; ACIDS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000076656100009 |
公开日期 | 2015-12-01 |
源URL | [http://ir.wipm.ac.cn/handle/112942/8307] ![]() |
专题 | 武汉物理与数学研究所_2011年以前论文发表(包括2011年) |
作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 2.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, XD,Zheng, G,Shen, LF,et al. Solid state NMR study of some substituted silatrane compounds[J]. ACTA CHIMICA SINICA,1998,56(10):986-989. |
APA | Zhang, XD,Zheng, G,Shen, LF,Ye, CH,Lu, ZR,&Zhuo, RX.(1998).Solid state NMR study of some substituted silatrane compounds.ACTA CHIMICA SINICA,56(10),986-989. |
MLA | Zhang, XD,et al."Solid state NMR study of some substituted silatrane compounds".ACTA CHIMICA SINICA 56.10(1998):986-989. |
入库方式: OAI收割
来源:武汉物理与数学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。