Solid state NMR study of some substituted silatrane compounds
文献类型:期刊论文
| 作者 | Zhang, XD; Zheng, G; Shen, LF; Ye, CH; Lu, ZR; Zhuo, RX |
| 刊名 | ACTA CHIMICA SINICA
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| 出版日期 | 1998 |
| 卷号 | 56期号:10页码:986-989 |
| 关键词 | solid state NMR silatrane molecular structure |
| 英文摘要 | Solid state NMR technique has been applied in the study of three synthesized silatranyl carboxylic acid compounds. The C-13, Si-29 and N-15 NMR chemical shifts of the compounds are obtained. The experimental results show that in the solid state the silatrane structures are distorted when there is a non-axial carboxyl substituent. In such cases, the strength of the N-Si dative bond is not normally reflected by the behavior of Si-29 and N-15 chemical shifts, and no hydrogen bond or salt is formed in the molecule. The experimental results and discussion are presented in detail. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | TRANSANNULAR INTERACTION ; AB-INITIO ; ACIDS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000076656100009 |
| 公开日期 | 2015-12-01 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8307] ![]() |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表(包括2011年) |
| 作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 2.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, XD,Zheng, G,Shen, LF,et al. Solid state NMR study of some substituted silatrane compounds[J]. ACTA CHIMICA SINICA,1998,56(10):986-989. |
| APA | Zhang, XD,Zheng, G,Shen, LF,Ye, CH,Lu, ZR,&Zhuo, RX.(1998).Solid state NMR study of some substituted silatrane compounds.ACTA CHIMICA SINICA,56(10),986-989. |
| MLA | Zhang, XD,et al."Solid state NMR study of some substituted silatrane compounds".ACTA CHIMICA SINICA 56.10(1998):986-989. |
入库方式: OAI收割
来源:武汉物理与数学研究所
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