Synthesis, mechanism and NMR spectra of lanthanide complexes with a novel unsymmetrical Schiff base
文献类型：期刊论文
| 作者 | Yao, KM; Zhou, W; Lu, G; Shen, LF |
| 刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| 出版日期 | 1999-04-01 |
| 卷号 | 42期号:2页码:164-169 |
| 关键词 | unsymmetrical Schiff base novel lanthanide complexes synthesis method NMR |
| 英文摘要 | Owing to its two unsymmetrical-NH2 groups sited on different terminals, 2, 6-diaminocaproic acid (lysine) was used as a reactant for synthesizing a novel unsymmetrical Schiff base with salicylaldehyde on one side and o-vaniliin on the other for the first time. It is a new way to synthesize such a special unsymmetrical Schiff base. It is named "hetero bis-Schiff base" for distinguishing it from others. The synthesis method, formation mechanism as well as twelve new lanthanide complexes with the above ligand are reported and discussed herein. They were characterized by elementary analysis, molar conductivity, IR-spectra and especially by H-1 and C-13 NMR spectra. The results obtained may provide a new promising method for synthesizing similar unsymmetrical Schiff bases and their complexes. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | GADOLINIUM COMPLEXES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000080130100008 |
| 公开日期 | 2015-12-01 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8404]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao, KM,Zhou, W,Lu, G,et al. Synthesis, mechanism and NMR spectra of lanthanide complexes with a novel unsymmetrical Schiff base[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,1999,42(2):164-169. |
| APA | Yao, KM,Zhou, W,Lu, G,&Shen, LF.(1999).Synthesis, mechanism and NMR spectra of lanthanide complexes with a novel unsymmetrical Schiff base.SCIENCE IN CHINA SERIES B-CHEMISTRY,42(2),164-169. |
| MLA | Yao, KM,et al."Synthesis, mechanism and NMR spectra of lanthanide complexes with a novel unsymmetrical Schiff base".SCIENCE IN CHINA SERIES B-CHEMISTRY 42.2(1999):164-169. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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