Synthesis, mechanism and NMR spectra of lanthanide complexes with an unsymmetrical Schiff base
文献类型：期刊论文
| 作者 | Yao, KM; Zhou, W; Lu, G; Shen, LF |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2000 |
| 卷号 | 58期号:10页码:1275-1279 |
| 关键词 | unsymmetrical Schiff base lanthanide complex liquid state 2D (13) C-(HCOSYNMR)-H-1 high resolution solid state C-13 NMR |
| 英文摘要 | Owing to two unsymmetrical -NH2 groups sited on different terminals, L-lysine was used as a reactant for synthesizing a novel unsymmetrical Schiff base with salicylaldehyde on one side and 2,4-dihydroxy benzaldehyde on the other one. Eight new lanthanide complexes with the Ligand above were synthesized and characterized by elemental analysis, TG-DTA, molar conductivity, IR and EPR spectra, especially by a 500 MHz NMR spectrometer for 2D C-13-H-1 COSY and their high resolution solid state C-13 NMR spectra. The synthesis method, formation mechanism, coordination sphere of the complexes have been suggested as well. The results obtained may provide a new promising method for synthesizing the similar unsymmetrical Schiff bases and their complexes. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | GADOLINIUM COMPLEXES ; EPR |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000165207800019 |
| 公开日期 | 2015-12-01 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8519]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao, KM,Zhou, W,Lu, G,et al. Synthesis, mechanism and NMR spectra of lanthanide complexes with an unsymmetrical Schiff base[J]. ACTA CHIMICA SINICA,2000,58(10):1275-1279. |
| APA | Yao, KM,Zhou, W,Lu, G,&Shen, LF.(2000).Synthesis, mechanism and NMR spectra of lanthanide complexes with an unsymmetrical Schiff base.ACTA CHIMICA SINICA,58(10),1275-1279. |
| MLA | Yao, KM,et al."Synthesis, mechanism and NMR spectra of lanthanide complexes with an unsymmetrical Schiff base".ACTA CHIMICA SINICA 58.10(2000):1275-1279. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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