Self-aggregation of dendritic poly(benzyl ether)-poly(acrylic acid), an amphiphilic block copolymer, studied by H-1 NMR
文献类型：期刊论文
| 作者 | Mao, SZ; Zhu, LY; Wang, TZ; Li, MZ; Wang, EJ; Miao, XJ; Fang, XW; Yuan, HZ; Du, YR |
| 刊名 | COLLOID AND POLYMER SCIENCE
 |
| 出版日期 | 2002 |
| 卷号 | 280期号:1页码:90-94 |
| 关键词 | self-diffusion coefficient NMR relaxation self-aggregate dendritic poly(benzyl ether)-poly(acrylic acid) amphiphilic block copolymer |
| 英文摘要 | The dynamic properties of the micelles of a novel synthesized amphiphilic block copolymer, dendritic poly(benzyl ether) -poly(acrylic acid) (Dendr.PBE-PAA), formed in aveous solutions were studied by the H-1 self-diffusion coefficient, relaxation measurements and 2D nuclear Overhauser enhancement spectroscopy. The experimental results show that Dendr.PBE-PAA molecules self-aggregate in aqueous solution. The dynamic properties of the Dendr.PBE-PAA micelles vary with their total concentration in the solution. The motion of the molecules in the micelles of a concentrated solution is more restricted than that in a less concentrated one. The main chains of PAA are densely packed in the surface layer of the hydrophobic core with the carboxyl side chain pointing to the aqueous medium and the hydrophobic phenoxy rings stay in the interior. The self-aggregate becomes larger as the degree of polymerization of PAA increases. However the phenoxy rings situated in the interior of the hydrophobic core become more loosely packed. n-Hexadecane is solubilized in the micelles. The optimal position of n-hexadecane is between the phenoxy rings next to the PAA chains. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical ; Polymer Science |
| 研究领域[WOS] | Chemistry ; Polymer Science |
| 关键词[WOS] | DIFFUSION ; MICELLES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000173550000014 |
| 公开日期 | 2015-12-08 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8694]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 2.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Mao, SZ,Zhu, LY,Wang, TZ,et al. Self-aggregation of dendritic poly(benzyl ether)-poly(acrylic acid), an amphiphilic block copolymer, studied by H-1 NMR[J]. COLLOID AND POLYMER SCIENCE,2002,280(1):90-94. |
| APA | Mao, SZ.,Zhu, LY.,Wang, TZ.,Li, MZ.,Wang, EJ.,...&Du, YR.(2002).Self-aggregation of dendritic poly(benzyl ether)-poly(acrylic acid), an amphiphilic block copolymer, studied by H-1 NMR.COLLOID AND POLYMER SCIENCE,280(1),90-94. |
| MLA | Mao, SZ,et al."Self-aggregation of dendritic poly(benzyl ether)-poly(acrylic acid), an amphiphilic block copolymer, studied by H-1 NMR".COLLOID AND POLYMER SCIENCE 280.1(2002):90-94. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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