Crystal structure and EPR spectra of cis-dioxo-molybdenum(V) complex with o-aminophenol
文献类型：期刊论文
| 作者 | Lu, XM; Lu, JF; Mao, XA |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2002-06-01 |
| 卷号 | 20期号:6页码:617-621 |
| 关键词 | cis-dioxo-molybdenum(V) complex anion o-aminophenol oxomolybdoenzyme X-ray crystallography EPR spectra |
| 英文摘要 | The paramagnetic cis-dioxo-molybdenum (V) complex, [NH2CH2CH2NH3](3)[(MoO2)-O-V(HNC6H4O)(2)] was obtained by the reaction of tetra-butyl ammonium beta-octamolybdate with o-aminophenol and ethylenediamine in the mixed solvent of CH3OH and CH3CN, and characterized by IR, NMR, EPR spectroscopy and X-ray diffraction analysis. The determination of single crystal X-ray analysis revealed that the central Mo-V ion metal center exhibits distorted octahedral coordination with cis-dioxo o-aminophenol. The EPR spectra of both the complex and flavoenzyme show similarly. Thus it suggests that the complex anion [(MoO2)-O-V (HNC6H4O)(2)](3-) and flavoenzyme have related structure feature. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ACTIVE-SITES ; TUNGSTOENZYMES ; REDUCTASE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000176074100018 |
| 公开日期 | 2015-12-08 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8715]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 2.Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China 3.Peking Univ, Med Sci Ctr, State Key Lab Nat & Biomimet Drugs, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, XM,Lu, JF,Mao, XA. Crystal structure and EPR spectra of cis-dioxo-molybdenum(V) complex with o-aminophenol[J]. CHINESE JOURNAL OF CHEMISTRY,2002,20(6):617-621. |
| APA | Lu, XM,Lu, JF,&Mao, XA.(2002).Crystal structure and EPR spectra of cis-dioxo-molybdenum(V) complex with o-aminophenol.CHINESE JOURNAL OF CHEMISTRY,20(6),617-621. |
| MLA | Lu, XM,et al."Crystal structure and EPR spectra of cis-dioxo-molybdenum(V) complex with o-aminophenol".CHINESE JOURNAL OF CHEMISTRY 20.6(2002):617-621. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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