Hydrothermal synthesis and structural characterization of three organically templated titanium phosphates: Ti-2(HPO4)(2)(PO4)(2)center dot C2N2H10, Ti-3(H2PO4)(HPO4)(3.5)(PO4)(2)center dot C2N2H10, and Ti-7(HPO4)(6)(PO4)(6)center dot C3N2H12
文献类型：期刊论文
| 作者 | Liu, YL; Shi, Z; Fu, YL; Chen, W; Li, BZ; Hua, J; Liu, WY; Deng, F; Pang, WQ |
| 刊名 | CHEMISTRY OF MATERIALS
 |
| 出版日期 | 2002-04-01 |
| 卷号 | 14期号:4页码:1555-1563 |
| 英文摘要 | Three organically templated titanium phosphates with the formulas Ti-2(HPO4)(2)(PO4)(2). C2N2H10 (1), Ti-3(H2PO4)(HPO4)(3.5)(PO4)(2).C2N2H10 (2), and Ti-7(HPO4)(6)(PO4)(6).C3N2H12 (3) have been prepared hydrothermally from titanium powder, phosphoric acid, and structure-directing organic amines. The as-synthesized products are characterized by powder X-ray diffraction, P-31 MAS NMR spectroscopy, IR spectroscopy, and thermogravimetric and differential thermal analyses (TG-DTA). The structures have been solved by single-crystal X-ray diffraction analysis. Crystal data for 1: triclinic, P (1) over bar, a = 6.3066(17) Angstrom, b = 10.181(4) Angstrom, c = 12.644(3) Angstrom, alpha = 102.14(2)degrees, beta = 102.49(3)degrees, gamma = 90.00(2)degrees, Z = 2. Crystal data for 2: triclinic, P (1) over bar, a = 10,3183(9) Angstrom, b = 10.7501(10) Angstrom, c = 10.8315(10) Angstrom, alpha = 73.436(2)degrees, beta = 79.648(2)degrees, gamma = 83.260(2)degrees, Z = 2. Crystal data for 3: trigonal, R (3) over bar, a = 16.4993(15) Angstrom, b = 16.4993(15) Angstrom, c = 12.704(3) Angstrom, Z = 3. Their frameworks are all built up with TiO6 octahedra and PO4, PO2(OH)(2), PO3(OH) and/or PO2(=O)(OH) tetrahedral units. Compound 1 is an ethylenediamine intercalated layered titanium phosphate in which the layers are similar to that of gamma-type titanium phosphate. Both 2 and 3 are of open-framework type, and the diprontonated organic amine molecules are entrapped in 12-membered-ring channels for 2 and 8-membered-ring channels for 3. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Materials Science |
| 关键词[WOS] | CRYSTAL-STRUCTURE ; TOPOLOGY |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000175028700017 |
| 公开日期 | 2015-12-08 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8786]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Lab Nucl Magnet Resonance, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, YL,Shi, Z,Fu, YL,et al. Hydrothermal synthesis and structural characterization of three organically templated titanium phosphates: Ti-2(HPO4)(2)(PO4)(2)center dot C2N2H10, Ti-3(H2PO4)(HPO4)(3.5)(PO4)(2)center dot C2N2H10, and Ti-7(HPO4)(6)(PO4)(6)center dot C3N2H12[J]. CHEMISTRY OF MATERIALS,2002,14(4):1555-1563. |
| APA | Liu, YL.,Shi, Z.,Fu, YL.,Chen, W.,Li, BZ.,...&Pang, WQ.(2002).Hydrothermal synthesis and structural characterization of three organically templated titanium phosphates: Ti-2(HPO4)(2)(PO4)(2)center dot C2N2H10, Ti-3(H2PO4)(HPO4)(3.5)(PO4)(2)center dot C2N2H10, and Ti-7(HPO4)(6)(PO4)(6)center dot C3N2H12.CHEMISTRY OF MATERIALS,14(4),1555-1563. |
| MLA | Liu, YL,et al."Hydrothermal synthesis and structural characterization of three organically templated titanium phosphates: Ti-2(HPO4)(2)(PO4)(2)center dot C2N2H10, Ti-3(H2PO4)(HPO4)(3.5)(PO4)(2)center dot C2N2H10, and Ti-7(HPO4)(6)(PO4)(6)center dot C3N2H12".CHEMISTRY OF MATERIALS 14.4(2002):1555-1563. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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