中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Ultrasonic-induced degradation of pentachlorophenol

文献类型:期刊论文

作者Shen, ZZ; Cheng, JZ; Wu, SJ
刊名ACTA CHIMICA SINICA
出版日期2003-12-01
卷号61期号:12页码:2016-2019
关键词sonochemistry Fenton type reagent bi-frequency pentachlorophenol hydroxy radical
英文摘要The presence of human-derived or naturally occurring volatile or nonvolatile toxic organic compounds in drinking water has become a problem of international concern. The presence of some toxic organic compounds in a few parts per billion is enough to render a water supply unpotable because it is harmful to long-term health, even though the water may have no discernible taste and odor. So waste water must be treated. There are several reports about water treatment in early literatures which use the power ultrasound wave to degrade the organic compounds in water. The chemical effects of ultrasound derive from acoustic cavitation. Cavitation is a source of radicals, especially the hydroxy radical, .OH, the very strong and nonspecific oxide which escapes out of the bubble and reacts rapidly with compounds in solution. In this paper, degradation effects of ultrasound on pentachlorophenol (PCP) is researched. PCP is treated by low frequency (16 kHz), high frequency [(800 +/- 1) kHz], and bi-frequency (combined of 16 kHz and 800 kHz) ultrasound wave, respectively. The results show that the rate of PCP degradation under the same conditions is highest at bi-frequency, lowest at 16 kHz. In the presence of Fenton type reagent the rate of PCP degradation is highest at bi-frequency which is 20.93 times as high as that of the stirring system without ultrasound wave. The ratios are 4.91 and 1.06 at 800 and 16 kHz, respectively. The studies show that the bi-frequency ultrasound is an effective method for pollutants degradation, but it need to make further study.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]SONOCHEMICAL DEGRADATION ; ORGANIC-COMPOUNDS ; AQUEOUS-SOLUTION
收录类别SCI
语种英语
WOS记录号WOS:000187533900025
公开日期2015-12-08
源URL[http://ir.wipm.ac.cn/handle/112942/8929]  
专题武汉物理与数学研究所_2011年以前论文发表(包括2011年)
作者单位1.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China
2.Shaanxi Normal Univ, Inst Appl Acoust, Xian 710062, Peoples R China
推荐引用方式
GB/T 7714
Shen, ZZ,Cheng, JZ,Wu, SJ. Ultrasonic-induced degradation of pentachlorophenol[J]. ACTA CHIMICA SINICA,2003,61(12):2016-2019.
APA Shen, ZZ,Cheng, JZ,&Wu, SJ.(2003).Ultrasonic-induced degradation of pentachlorophenol.ACTA CHIMICA SINICA,61(12),2016-2019.
MLA Shen, ZZ,et al."Ultrasonic-induced degradation of pentachlorophenol".ACTA CHIMICA SINICA 61.12(2003):2016-2019.

入库方式: OAI收割

来源:武汉物理与数学研究所

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