UV photodissociation dynamics of n-alkyl bromide
文献类型：期刊论文
| 作者 | Zhu, RS; Tang, BF; Ji, L; Tang, Y; Zhang, S; Wang, YM; Zhang, B |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2004-10-10 |
| 卷号 | 25期号:10页码:1885-1888 |
| 关键词 | n-alkyl bromide REMPI-TOFMS photodissociation dynamics branching ratio |
| 英文摘要 | With the deep development of environmental investigation, some alkyl bromides of higher homolog(e. g., C2H5Br, n-C3H7Br, n-C4Hg9Br) in the lower stratosphere have attracted a little attention in recent years. But the photodissociation dynamics of them have not been studied. In this work, we reported the photodissociation dynamics of n-alkyl bromides R-Br (R = n-alkyl radical) (C2H5Br, n-C3H7Br, n-C4H9Br) at 234 and 267 nm using resonace-enhanced multiphoton ionization (REMPI) with time-flight mass spectrometry (TOF-MS) and the goal was to study the dependencies of the relative quantum yields of phi(Br*) and phi(Br) on photon energy and the molecular complexity. The measured values of the phi(Br *) were found to be phi(Br*)(234nm) = 0.286 and (Br*)(267nm) = 0.338 for C2H5Br, phi(Br*)(234nm) = 0.356 and phi(Br*)(267nm) =0.294 for n-C3H7Br, phi(Br*)(234nm) = 0.428 and phi(Br*)(267nm) = 0.341 for n-C4H9Br. The results of phi(Br *) clearly showed an increasing tendency with the increase of molecular complexity at 234 nm (C2H5Br |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | OZONE DEPLETION POTENTIALS ; H-ATOM PRODUCTION ; ETHYL-BROMIDE ; CHLOROBROMOMETHANE CH2CLBR ; MULTIPHOTON IONIZATION ; BRANCHING RATIOS ; PHOTOLYSIS ; IODIDES ; CH3BR ; PHOTOIONIZATION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000224628000027 |
| 公开日期 | 2015-12-08 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8973]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, RS,Tang, BF,Ji, L,et al. UV photodissociation dynamics of n-alkyl bromide[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,25(10):1885-1888. |
| APA | Zhu, RS.,Tang, BF.,Ji, L.,Tang, Y.,Zhang, S.,...&Zhang, B.(2004).UV photodissociation dynamics of n-alkyl bromide.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,25(10),1885-1888. |
| MLA | Zhu, RS,et al."UV photodissociation dynamics of n-alkyl bromide".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 25.10(2004):1885-1888. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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