Mass analyzed threshold ionization spectroscopy of p-fluorophenol cation and the p-fluoro substitution effect
文献类型：期刊论文
| 作者 | Zhang, B; Li, CY; Su, HW; Lin, JL; Tzeng, WB |
| 刊名 | CHEMICAL PHYSICS LETTERS
 |
| 出版日期 | 2004-05-21 |
| 卷号 | 390期号:1-3页码:65-70 |
| 英文摘要 | The origin of the S1<--S0 electronic transition and the adiabatic ionization energy of p-fluorophenol are determined to be 35117+/-2 and 68577+/-5 cm(-1), which are lower than those of phenol by 1232 and 48 cm(-1), respectively. Most of the active vibrations in the electronic excited S-1 and cationic ground D-0 states are related to the in-plane ring modes. The p-fluoro substitution not only causes red shifts in the transition energies but also leads to a decrease in the frequencies of the observed vibrations. The present experimental findings are well supported by our ab initio and density functional calculations. (C) 2004 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
| 研究领域[WOS] | Chemistry ; Physics |
| 关键词[WOS] | SUPERSONIC JET ; EXCITATION ; SPECTRA ; ENERGY ; PHENOL ; ALKYLPHENOLS ; COMPLEXES ; STATES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000221628400013 |
| 公开日期 | 2015-12-08 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/9014]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Acad Sinica, Sect 4, Taipei 106, Taiwan 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 3.Shanxi Univ, Dept Elect, Taiyuan 030006, Shanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, B,Li, CY,Su, HW,et al. Mass analyzed threshold ionization spectroscopy of p-fluorophenol cation and the p-fluoro substitution effect[J]. CHEMICAL PHYSICS LETTERS,2004,390(1-3):65-70. |
| APA | Zhang, B,Li, CY,Su, HW,Lin, JL,&Tzeng, WB.(2004).Mass analyzed threshold ionization spectroscopy of p-fluorophenol cation and the p-fluoro substitution effect.CHEMICAL PHYSICS LETTERS,390(1-3),65-70. |
| MLA | Zhang, B,et al."Mass analyzed threshold ionization spectroscopy of p-fluorophenol cation and the p-fluoro substitution effect".CHEMICAL PHYSICS LETTERS 390.1-3(2004):65-70. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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