Ultralow Thermal Conductivity of Atomic/Molecular Layer-Deposited Hybrid Organic-Inorganic Zincone Thin Films
文献类型：期刊论文
| 作者 | Liu, Jun1; Yoon, Byunghoon2; Kuhlmann, Eli1; Tian, Miao1; Zhu, Jie3; George, Steven M.1,2; Lee, Yung-Cheng1; Yang, Ronggui1 |
| 刊名 | NANO LETTERS
 |
| 出版日期 | 2013-11-01 |
| 卷号 | 13期号:11页码:5594-5599 |
| 关键词 | Atomic layer deposition molecular layer deposition hybrid organic-inorganic material thermal conductivity |
| 英文摘要 | Atomic layer deposition (ALD) and molecular layer deposition (MLD) techniques with atomic level control enable a new class of hybrid organic inorganic materials with improved functionality. In this work, the cross-plane thermal conductivity and volumetric heat capacity of three types of hybrid organic inorganic zincone thin films enabled by MLD processes and alternate AID MILD processes were measured using the frequency-dependent time-domain thermoreflectance method. We revealed the critical role of backbone flexibility in the structural morphology and thermal conductivity of MLD zincone thin films by comparing the thermal conductivity of MILD zincone films with an aliphatic backbone to that with aromatic backbone. Much lower thermal conductivity values were obtained in ALD/MLD-enabled hybrid organic inorganic zincone thin films compared to that of the ALD-enabled W/Al2O3 nanolaminates reported by Costescu et al. [Science 2004, 303, 989-990], which suggests that the dramatic material difference between organic and inorganic materials may provide a route for producing materials with ultralow thermal conductivity. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| 研究领域[WOS] | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 关键词[WOS] | ETHYLENE-GLYCOL ; TRIMETHYLALUMINUM ; TRANSPORT ; NM |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000327111700094 |
| 公开日期 | 2015-12-22 |
| 源URL | [http://ir.etp.ac.cn/handle/311046/98801]  |
| 专题 | 工程热物理研究所_中国科学院工程热物理所（论文库）_期刊论文（SCI） |
| 作者单位 | 1.Univ Colorado, Dept Mech Engn, Boulder, CO 80309 USA 2.Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA 3.Chinese Acad Sci, Inst Engn Thermophys, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Jun,Yoon, Byunghoon,Kuhlmann, Eli,et al. Ultralow Thermal Conductivity of Atomic/Molecular Layer-Deposited Hybrid Organic-Inorganic Zincone Thin Films[J]. NANO LETTERS,2013,13(11):5594-5599. |
| APA | Liu, Jun.,Yoon, Byunghoon.,Kuhlmann, Eli.,Tian, Miao.,Zhu, Jie.,...&Yang, Ronggui.(2013).Ultralow Thermal Conductivity of Atomic/Molecular Layer-Deposited Hybrid Organic-Inorganic Zincone Thin Films.NANO LETTERS,13(11),5594-5599. |
| MLA | Liu, Jun,et al."Ultralow Thermal Conductivity of Atomic/Molecular Layer-Deposited Hybrid Organic-Inorganic Zincone Thin Films".NANO LETTERS 13.11(2013):5594-5599. |
入库方式： OAI收割
来源：工程热物理研究所
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