Continuous sorption-enhanced steam reforming of glycerol to high-purity hydrogen production
文献类型：期刊论文
| 作者 | Dou, Binlin1; Wang, Chao1; Chen, Haisheng2; Song, Yongchen1; Xie, Baozheng1 |
| 刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
 |
| 出版日期 | 2013-09-10 |
| 卷号 | 38期号:27页码:11902-11909 |
| 关键词 | Sorption-enhanced steam reforming Glycerol High-purity hydrogen NiO/NiAl2O4 catalyst CaO sorbent |
| 英文摘要 | In this study, the continuous sorption-enhanced steam reforming of glycerol to high-purity hydrogen production by a simultaneous flow concept of catalyst and sorbent for reaction and regeneration using two moving-bed reactors has been evaluated experimentally. A Ni-based catalyst (NiO/NiAl2O4) and a lime sorbent (CaO) were used for glycerol steam reforming with and without in-situ CO2 removal at 500 degrees C and 600 degrees C. The simultaneous regeneration of catalyst and sorbent was carried out with the mixture gas of N-2 and steam at 900 degrees C. The product gases were measured by a GC gas analyzer. It is obvious that the amounts of CO2, CO and CH4 were reduced in the sorption-enhanced steam reforming of glycerol, and the H-2 concentration is greatly increased in the pre-CO2 breakthrough periods within 10 min both 500 degrees C and 600 degrees C. The extended time of operation for high-purity hydrogen production and CO2 capture was obtained by the continuous sorption-enhanced steam reforming of glycerol. High-purity H-2 products of 93.9% and 96.1% were produced at 500 degrees C and 600 degrees C and very small amounts of CO2, CH4 and CO were formed. The decay in activity during the continuous reaction-regeneration of catalyst and sorbent was not observed. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
| 研究领域[WOS] | Chemistry ; Electrochemistry ; Energy & Fuels |
| 关键词[WOS] | SUPPORTED METAL-CATALYSTS ; FIXED-BED REACTOR ; RENEWABLE HYDROGEN ; METHANE ; MG ; AL ; SORBENT ; ETHANOL |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000324563200026 |
| 公开日期 | 2015-12-22 |
| 源URL | [http://ir.etp.ac.cn/handle/311046/98804]  |
| 专题 | 工程热物理研究所_中国科学院工程热物理所（论文库）_期刊论文（SCI） |
| 作者单位 | 1.Dalian Univ Technol, Minist Educ, Key Lab Ocean Energy Utilizat & Energy Conservat, Sch Energy & Power Engn, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Inst Engn Thermophys, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dou, Binlin,Wang, Chao,Chen, Haisheng,et al. Continuous sorption-enhanced steam reforming of glycerol to high-purity hydrogen production[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2013,38(27):11902-11909. |
| APA | Dou, Binlin,Wang, Chao,Chen, Haisheng,Song, Yongchen,&Xie, Baozheng.(2013).Continuous sorption-enhanced steam reforming of glycerol to high-purity hydrogen production.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,38(27),11902-11909. |
| MLA | Dou, Binlin,et al."Continuous sorption-enhanced steam reforming of glycerol to high-purity hydrogen production".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 38.27(2013):11902-11909. |
入库方式： OAI收割
来源：工程热物理研究所
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