NOx and N2O precursors (NH3 and HCN) from biomass pyrolysis: interaction between amino acid and mineral matter
文献类型：期刊论文
| 作者 | Ren, Qiangqiang1,2; Zhao, Changsui2 |
| 刊名 | APPLIED ENERGY
 |
| 出版日期 | 2013-12-01 |
| 卷号 | 112页码:170-174 |
| 关键词 | Biomass Amino acid Pyrolysis NOx and N2O precursor Mineral matter FT-IR |
| 英文摘要 | Mineral matter in biomass influences nitrogen chemistry during pyrolysis. Amino acids, selected as the model compound in biomass, were pyrolyzed with the major mineral matters in biomass (potassium, calcium and iron) at 800 degrees C to investigate the effect of mineral matter on the distribution of N-containing species from amino acid pyrolysis. HCN and NH3 were detected online with a Fourier transform infrared (FT-IR) spectrometer. The extent of interaction between amino acid and the mineral matter was determined by comparing the yields of HCN and NH3 from pyrolysis of amino acids with mineral matters with those from amino acid pyrolysis under the same condition. The results indicate that yields of HCN and NH3 and nitrogen conversion pathway from amino acid pyrolysis are influenced by the mineral matter. Mineral matter has catalytic effects on the primary decomposition reaction pathway of amino acid as well as the secondary cracking pathway of 2,5-piperazinedione. For amino acids with reactive side chains, the mineral matter also has catalytic effects on thermal cracking of nitrogen-containing char. (C) 2013 Elsevier Ltd. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Energy & Fuels ; Engineering, Chemical |
| 研究领域[WOS] | Energy & Fuels ; Engineering |
| 关键词[WOS] | THERMAL-DECOMPOSITION ; FUEL-NITROGEN ; CO-PYROLYSIS ; CONVERSION ; PHENYLALANINE ; WOOD ; COMBUSTION ; PRODUCTS ; BEHAVIOR ; SYSTEMS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000329377800017 |
| 源URL | [http://ir.etp.ac.cn/handle/311046/98853]  |
| 专题 | 工程热物理研究所_中国科学院工程热物理所（论文库）_期刊论文（SCI） |
| 作者单位 | 1.Chinese Acad Sci, Inst Engn Thermophys, Beijing 100190, Peoples R China 2.Southeast Univ, Sch Energy & Environm, Nanjing 210096, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren, Qiangqiang,Zhao, Changsui. NOx and N2O precursors (NH3 and HCN) from biomass pyrolysis: interaction between amino acid and mineral matter[J]. APPLIED ENERGY,2013,112:170-174. |
| APA | Ren, Qiangqiang,&Zhao, Changsui.(2013).NOx and N2O precursors (NH3 and HCN) from biomass pyrolysis: interaction between amino acid and mineral matter.APPLIED ENERGY,112,170-174. |
| MLA | Ren, Qiangqiang,et al."NOx and N2O precursors (NH3 and HCN) from biomass pyrolysis: interaction between amino acid and mineral matter".APPLIED ENERGY 112(2013):170-174. |
入库方式： OAI收割
来源：工程热物理研究所
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