Equivalent characteristic spectrum analysis in TG-MS system
文献类型：期刊论文
| 作者 | Xia, Hongde; Wei, Kai |
| 刊名 | THERMOCHIMICA ACTA
 |
| 出版日期 | 2015-02-20 |
| 卷号 | 602页码:15-21 |
| 关键词 | Equivalent characteristic spectrum analysis Quantitative analysis Calibration Relative sensitivity Evolve gas analysis |
| 英文摘要 | A novel method of equivalent characteristic spectrum analysis (ECSA) was developed to analyze the mass spectrum of TG-MS system according to the operating principle of TG-MS coupling system. In ECSA, the characteristic spectra and the relative sensitivity were calibrated for all tested gases. This method effectively separated the mass spectrum, eliminated the mass discrimination and temperature-dependent effect, even if there were some overlaps at characteristic peak. Based on the decomposition of CaCO3 and CaC2O4, actual flow rate and concentration of individual component in evolved gas have been dynamically determined. The analyzed mass flow rates of evolved gases agree well with ECSA and the experimental data from TG analysis. Moreover, the stability of calibration and quantitative analysis by ECSA method were discussed. (C) 2014 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Analytical ; Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | THERMAL-ANALYSIS ; MASS-SPECTROMETER |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000350076300003 |
| 公开日期 | 2015-12-22 |
| 源URL | [http://ir.etp.ac.cn/handle/311046/98928]  |
| 专题 | 工程热物理研究所_中国科学院工程热物理所（论文库）_期刊论文（SCI） |
| 作者单位 | Chinese Acad Sci, Inst Engn Thermophys, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Hongde,Wei, Kai. Equivalent characteristic spectrum analysis in TG-MS system[J]. THERMOCHIMICA ACTA,2015,602:15-21. |
| APA | Xia, Hongde,&Wei, Kai.(2015).Equivalent characteristic spectrum analysis in TG-MS system.THERMOCHIMICA ACTA,602,15-21. |
| MLA | Xia, Hongde,et al."Equivalent characteristic spectrum analysis in TG-MS system".THERMOCHIMICA ACTA 602(2015):15-21. |
入库方式： OAI收割
来源：工程热物理研究所
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