中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Characterization and Catalytic Activity of CeO2-Ni/Mo/SBA-15 Catalysts for Carbon Dioxide Reforming of Methane

文献类型:期刊论文

作者Huang Jian1,3; Ma Renxiong2; Gao Zhihua1; Shen Chaofeng1; Huang Wei1
刊名CHINESE JOURNAL OF CATALYSIS
出版日期2012-04-01
卷号33期号:4页码:637-644
关键词carbon dioxide reforming methane nickel molybdenum mesoporous molecular sieve SBA-15 cerium-promoted
英文摘要A Ni/Mo/SBA-15 catalyst was modified with CeO2 and compared with the unmodified catalyst. The catalysts were characterized by N-2 adsorption, CO2 temperature-programmed desorption, H-2 temperature-programmed reduction, Fourier transform infrared spectrometer, X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy. Both the Ni/Mo/SBA-15 and CeO2/Ni/Mo/SBA-15 catalysts gave good catalytic activities at atmospheric pressure. The CeO2 impregnated Ni/Mo/SBA-15 catalyst exhibited excellent stability at 800 degrees C for 100 h on stream, and after the reaction, carbon deposits were not formed on the catalyst. The Ni/Mo/SBA-15 and CeO2/Ni/Mo/SBA-15 catalysts had a regular hexagonal mesoporous structure. The nickel species and the Ce-Mo oxide components were all in the SBA-15 mesopores. This prevented carbon deposition and sintering of the nickel species in the CeO2/Ni/Mo/SBA-15 catalyst.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]SYNTHESIS GAS ; CO2 ; CH4 ; NI ; SYNGAS ; CEO2 ; PLASMA ; SILICA ; SBA-15 ; H-2
收录类别SCI
语种英语
WOS记录号WOS:000303360300008
公开日期2015-12-22
源URL[http://ir.etp.ac.cn/handle/311046/101518]  
专题工程热物理研究所_中国科学院工程热物理所(论文库)_期刊论文(SCI)
作者单位1.Taiyuan Univ Technol, Minist Educ & Shanxi Prov, Key Lab Coal Sci & Technol, Taiyuan 030024, Shanxi, Peoples R China
2.Chinese Acad Sci, Inst Engn Thermophys, Beijing 100190, Peoples R China
3.Yuncheng Univ, Dept Appl Chem, Yuncheng 044000, Shanxi, Peoples R China
推荐引用方式
GB/T 7714
Huang Jian,Ma Renxiong,Gao Zhihua,et al. Characterization and Catalytic Activity of CeO2-Ni/Mo/SBA-15 Catalysts for Carbon Dioxide Reforming of Methane[J]. CHINESE JOURNAL OF CATALYSIS,2012,33(4):637-644.
APA Huang Jian,Ma Renxiong,Gao Zhihua,Shen Chaofeng,&Huang Wei.(2012).Characterization and Catalytic Activity of CeO2-Ni/Mo/SBA-15 Catalysts for Carbon Dioxide Reforming of Methane.CHINESE JOURNAL OF CATALYSIS,33(4),637-644.
MLA Huang Jian,et al."Characterization and Catalytic Activity of CeO2-Ni/Mo/SBA-15 Catalysts for Carbon Dioxide Reforming of Methane".CHINESE JOURNAL OF CATALYSIS 33.4(2012):637-644.

入库方式: OAI收割

来源:工程热物理研究所

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