Characterization and Catalytic Activity of CeO2-Ni/Mo/SBA-15 Catalysts for Carbon Dioxide Reforming of Methane
文献类型:期刊论文
作者 | Huang Jian1,3; Ma Renxiong2; Gao Zhihua1; Shen Chaofeng1; Huang Wei1 |
刊名 | CHINESE JOURNAL OF CATALYSIS
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出版日期 | 2012-04-01 |
卷号 | 33期号:4页码:637-644 |
关键词 | carbon dioxide reforming methane nickel molybdenum mesoporous molecular sieve SBA-15 cerium-promoted |
英文摘要 | A Ni/Mo/SBA-15 catalyst was modified with CeO2 and compared with the unmodified catalyst. The catalysts were characterized by N-2 adsorption, CO2 temperature-programmed desorption, H-2 temperature-programmed reduction, Fourier transform infrared spectrometer, X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy. Both the Ni/Mo/SBA-15 and CeO2/Ni/Mo/SBA-15 catalysts gave good catalytic activities at atmospheric pressure. The CeO2 impregnated Ni/Mo/SBA-15 catalyst exhibited excellent stability at 800 degrees C for 100 h on stream, and after the reaction, carbon deposits were not formed on the catalyst. The Ni/Mo/SBA-15 and CeO2/Ni/Mo/SBA-15 catalysts had a regular hexagonal mesoporous structure. The nickel species and the Ce-Mo oxide components were all in the SBA-15 mesopores. This prevented carbon deposition and sintering of the nickel species in the CeO2/Ni/Mo/SBA-15 catalyst. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
研究领域[WOS] | Chemistry ; Engineering |
关键词[WOS] | SYNTHESIS GAS ; CO2 ; CH4 ; NI ; SYNGAS ; CEO2 ; PLASMA ; SILICA ; SBA-15 ; H-2 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000303360300008 |
公开日期 | 2015-12-22 |
源URL | [http://ir.etp.ac.cn/handle/311046/101518] ![]() |
专题 | 工程热物理研究所_中国科学院工程热物理所(论文库)_期刊论文(SCI) |
作者单位 | 1.Taiyuan Univ Technol, Minist Educ & Shanxi Prov, Key Lab Coal Sci & Technol, Taiyuan 030024, Shanxi, Peoples R China 2.Chinese Acad Sci, Inst Engn Thermophys, Beijing 100190, Peoples R China 3.Yuncheng Univ, Dept Appl Chem, Yuncheng 044000, Shanxi, Peoples R China |
推荐引用方式 GB/T 7714 | Huang Jian,Ma Renxiong,Gao Zhihua,et al. Characterization and Catalytic Activity of CeO2-Ni/Mo/SBA-15 Catalysts for Carbon Dioxide Reforming of Methane[J]. CHINESE JOURNAL OF CATALYSIS,2012,33(4):637-644. |
APA | Huang Jian,Ma Renxiong,Gao Zhihua,Shen Chaofeng,&Huang Wei.(2012).Characterization and Catalytic Activity of CeO2-Ni/Mo/SBA-15 Catalysts for Carbon Dioxide Reforming of Methane.CHINESE JOURNAL OF CATALYSIS,33(4),637-644. |
MLA | Huang Jian,et al."Characterization and Catalytic Activity of CeO2-Ni/Mo/SBA-15 Catalysts for Carbon Dioxide Reforming of Methane".CHINESE JOURNAL OF CATALYSIS 33.4(2012):637-644. |
入库方式: OAI收割
来源:工程热物理研究所
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