中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Reversible optical switching of dirac point of graphene functionalized with azobenzene

文献类型:期刊论文

作者Deepshikha
刊名RUSSIAN JOURNAL OF GENERAL CHEMISTRY
出版日期2015-09-01
卷号85期号:9页码:2167-2173
关键词graphene photosensitive azobenzene covalent modification Raman spectroscopy optoelectronic properties
英文摘要Graphene has exceptional electronic, optical, mechanical and thermal properties that determine its great potential in electronic, optoelectronic and sensing applications. In this study graphene has been covalently functionalized with azobenzene (AB) photosensitizer. The field-effect transistor (FET) with AB-functionalized graphene exhibited the p-doping effect with hole concentration ca 4 x 10(12) cm(-2) and interesting optoelectronic behaviour. The Dirac point of graphene in the FET could be controlled by light modulation due to azobenzene reversible switching between cis and trans conformations upon UV and visible light irradiation. Cis structure formation was initiated by UV irradiation that induced the shift of the Dirac point of graphene toward positive gate voltage. The reverse process back to trans form occurred under visible light irradiation or in darkness inducing the shift of the Dirac point toward negative gate voltage. The effect was reproduced repeatedly.
收录类别SCI
语种英语
公开日期2015-12-22
源URL[http://ir.iccas.ac.cn/handle/121111/29139]  
专题化学研究所_分子动态与稳态结构实验室
作者单位Peking Univ, State Key Lab Struct Chem Unstable & Stable Speci, Coll Chem & Mol Engn, Ctr Nanochem,BNLMS, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Deepshikha. Reversible optical switching of dirac point of graphene functionalized with azobenzene[J]. RUSSIAN JOURNAL OF GENERAL CHEMISTRY,2015,85(9):2167-2173.
APA Deepshikha.(2015).Reversible optical switching of dirac point of graphene functionalized with azobenzene.RUSSIAN JOURNAL OF GENERAL CHEMISTRY,85(9),2167-2173.
MLA Deepshikha."Reversible optical switching of dirac point of graphene functionalized with azobenzene".RUSSIAN JOURNAL OF GENERAL CHEMISTRY 85.9(2015):2167-2173.

入库方式: OAI收割

来源:化学研究所

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