Reversible optical switching of dirac point of graphene functionalized with azobenzene
文献类型:期刊论文
作者 | Deepshikha |
刊名 | RUSSIAN JOURNAL OF GENERAL CHEMISTRY
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出版日期 | 2015-09-01 |
卷号 | 85期号:9页码:2167-2173 |
关键词 | graphene photosensitive azobenzene covalent modification Raman spectroscopy optoelectronic properties |
英文摘要 | Graphene has exceptional electronic, optical, mechanical and thermal properties that determine its great potential in electronic, optoelectronic and sensing applications. In this study graphene has been covalently functionalized with azobenzene (AB) photosensitizer. The field-effect transistor (FET) with AB-functionalized graphene exhibited the p-doping effect with hole concentration ca 4 x 10(12) cm(-2) and interesting optoelectronic behaviour. The Dirac point of graphene in the FET could be controlled by light modulation due to azobenzene reversible switching between cis and trans conformations upon UV and visible light irradiation. Cis structure formation was initiated by UV irradiation that induced the shift of the Dirac point of graphene toward positive gate voltage. The reverse process back to trans form occurred under visible light irradiation or in darkness inducing the shift of the Dirac point toward negative gate voltage. The effect was reproduced repeatedly. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2015-12-22 |
源URL | [http://ir.iccas.ac.cn/handle/121111/29139] ![]() |
专题 | 化学研究所_分子动态与稳态结构实验室 |
作者单位 | Peking Univ, State Key Lab Struct Chem Unstable & Stable Speci, Coll Chem & Mol Engn, Ctr Nanochem,BNLMS, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Deepshikha. Reversible optical switching of dirac point of graphene functionalized with azobenzene[J]. RUSSIAN JOURNAL OF GENERAL CHEMISTRY,2015,85(9):2167-2173. |
APA | Deepshikha.(2015).Reversible optical switching of dirac point of graphene functionalized with azobenzene.RUSSIAN JOURNAL OF GENERAL CHEMISTRY,85(9),2167-2173. |
MLA | Deepshikha."Reversible optical switching of dirac point of graphene functionalized with azobenzene".RUSSIAN JOURNAL OF GENERAL CHEMISTRY 85.9(2015):2167-2173. |
入库方式: OAI收割
来源:化学研究所
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