中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Triazatruxene based covalent organic framework and its quick-response fluorescence-on nature towards electron rich arenes

文献类型:期刊论文

作者Xie, Yun-Feng1; Ding, San-Yuan2; Liu, Jun-Min3; Wang, Wei2; Zheng, Qi-Yu1
刊名JOURNAL OF MATERIALS CHEMISTRY C
出版日期2015
卷号3期号:39页码:10066-10069
英文摘要Two new 2D covalent organic frameworks (COFs) with a regular honeycomb lattice, TAT-COF-1 and TAT-COF-2, were synthesized based on triazatruxene derivatives. The two COFs, especially TAT-COF-2, have a large BET surface area, good crystallinity, moderate to good hydrogen and carbon dioxide adsorption abilities and also possess good CO2/N-2 selectivity. When suspended in ethanol, the fluorescence of TAT-COF-2 could be enhanced or quenched by different solvents. It also shows a rapid fluorescence-on and fluorescence-off nature towards electron rich and deficient arene vapors, respectively. After being exposed to electron-rich arene vapors, the enhanced fluorescence intensity can be recovered to normal level after 5 minutes in an ambient atmosphere, which means the sample could be reused conveniently for detecting electron rich arene vapors.
收录类别SCI
语种英语
公开日期2015-12-22
源URL[http://ir.iccas.ac.cn/handle/121111/29122]  
专题化学研究所_分子识别与功能实验室
作者单位1.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
3.Sun Yat Sen Univ, Sch Chem & Chem Engn, Klghei Environm & Energy Chem, Guangzhou 510275, Guangdong, Peoples R China
推荐引用方式
GB/T 7714
Xie, Yun-Feng,Ding, San-Yuan,Liu, Jun-Min,et al. Triazatruxene based covalent organic framework and its quick-response fluorescence-on nature towards electron rich arenes[J]. JOURNAL OF MATERIALS CHEMISTRY C,2015,3(39):10066-10069.
APA Xie, Yun-Feng,Ding, San-Yuan,Liu, Jun-Min,Wang, Wei,&Zheng, Qi-Yu.(2015).Triazatruxene based covalent organic framework and its quick-response fluorescence-on nature towards electron rich arenes.JOURNAL OF MATERIALS CHEMISTRY C,3(39),10066-10069.
MLA Xie, Yun-Feng,et al."Triazatruxene based covalent organic framework and its quick-response fluorescence-on nature towards electron rich arenes".JOURNAL OF MATERIALS CHEMISTRY C 3.39(2015):10066-10069.

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来源:化学研究所

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