Chiral Primary Amine/Palladium Dual Catalysis for Asymmetric Allylic Alkylation of beta-Ketocarbonyl Compounds with Allylic Alcohols
文献类型：期刊论文
| 作者 | Zhou, Han; Zhang, Long; Xu, Changming; Luo, Sanzhong |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2015-10-19 |
| 卷号 | 54期号:43页码:12645-12648 |
| 关键词 | allylic alcohols asymmetric allylic alkylation chiral primary amines palladium beta-ketocarbonyl compounds |
| 英文摘要 | An efficient dual catalytic system composed of a chiral primary amine and a palladium complex was developed to promote the direct asymmetric allylic alkylation (AAA) of beta-ketocarbonyl compounds. In particular, the synergistic dual catalytic system enabled the AAA reaction of challenging acyclic aliphatic ketones, such as b-ketocarbonyl compounds and 1,3-diketones. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-12-22 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/29151]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Han,Zhang, Long,Xu, Changming,et al. Chiral Primary Amine/Palladium Dual Catalysis for Asymmetric Allylic Alkylation of beta-Ketocarbonyl Compounds with Allylic Alcohols[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2015,54(43):12645-12648. |
| APA | Zhou, Han,Zhang, Long,Xu, Changming,&Luo, Sanzhong.(2015).Chiral Primary Amine/Palladium Dual Catalysis for Asymmetric Allylic Alkylation of beta-Ketocarbonyl Compounds with Allylic Alcohols.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,54(43),12645-12648. |
| MLA | Zhou, Han,et al."Chiral Primary Amine/Palladium Dual Catalysis for Asymmetric Allylic Alkylation of beta-Ketocarbonyl Compounds with Allylic Alcohols".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 54.43(2015):12645-12648. |
入库方式： OAI收割
来源：化学研究所
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