Manganese-Catalyzed Direct Nucleophilic C(sp(2))-H Addition to Aldehydes and Nitriles
文献类型：期刊论文
| 作者 | Zhou, Bingwei; Hu, Yuanyuan; Wang, Congyang |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2015-11-09 |
| 卷号 | 54期号:46页码:13659-13663 |
| 关键词 | alcohols C-H activation carbonyl compounds Lewis acids manganese |
| 英文摘要 | Herein, a manganese-catalyzed nucleophilic addition of inert C(sp(2))H bonds to aldehydes and nitriles is disclosed by virtue of a dual activation strategy. The reactions feature mild reaction conditions, excellent regio- and stereoselectivity, and a wide substrate scope, which includes both aromatic and olefinic CH bonds, as well as a large variety of aldehydes and nitriles. Moreover, mechanistic studies shed light on possible catalytic cycles. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-12-22 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/29215]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Bingwei,Hu, Yuanyuan,Wang, Congyang. Manganese-Catalyzed Direct Nucleophilic C(sp(2))-H Addition to Aldehydes and Nitriles[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2015,54(46):13659-13663. |
| APA | Zhou, Bingwei,Hu, Yuanyuan,&Wang, Congyang.(2015).Manganese-Catalyzed Direct Nucleophilic C(sp(2))-H Addition to Aldehydes and Nitriles.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,54(46),13659-13663. |
| MLA | Zhou, Bingwei,et al."Manganese-Catalyzed Direct Nucleophilic C(sp(2))-H Addition to Aldehydes and Nitriles".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 54.46(2015):13659-13663. |
入库方式： OAI收割
来源：化学研究所
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