Two tandem multicomponent reactions for the synthesis of sequence-defined polymers
文献类型：期刊论文
| 作者 | Yang, Lu1; Zhang, Ze1; Cheng, Bofei1; You, Yezi1; Wu, Decheng2; Hong, Chunyan1 |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2015-11-01 |
| 卷号 | 58期号:11页码:1734-1740 |
| 关键词 | multicomponent polymerizations multicomponent reaction sequence-defined polymers Passerini reaction |
| 英文摘要 | Multicomponent polymerizations have become powerful tools for the construction of sequence-defined polymers. Although the Passerini multicomponent reaction has been widely used in the synthesis of sequence-defined polymers, the tandem usage of the Passerini multicomponent reaction and other multicomponent reactions in one-pot for the synthesis of sequence-defined polymers has not been developed until now. In this contribution, we report the tandem usage of the Passerini three-component reaction and the three-component amine-thiol-ene conjugation reaction in one pot for the synthesis of sequence-defined polymers. The Passerini reaction between methacrylic acid, adipaldehyde, and 2-isocyanobutanoate was carried out, affording a new molecule containing two alkene units. Subsequently, an amine and a thiolactone were added to the reaction system, whereupon the three-component amine-thiol-ene conjugating reaction occurred to yield a sequence-defined polymer. This method offers more rapid access to sequence-defined polymers with high molecular diversity and complexity. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-12-22 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/29128]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Univ Sci & Technol China, Dept Polymer Sci & Engn, Key Lab Soft Matter Chem, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Lu,Zhang, Ze,Cheng, Bofei,et al. Two tandem multicomponent reactions for the synthesis of sequence-defined polymers[J]. SCIENCE CHINA-CHEMISTRY,2015,58(11):1734-1740. |
| APA | Yang, Lu,Zhang, Ze,Cheng, Bofei,You, Yezi,Wu, Decheng,&Hong, Chunyan.(2015).Two tandem multicomponent reactions for the synthesis of sequence-defined polymers.SCIENCE CHINA-CHEMISTRY,58(11),1734-1740. |
| MLA | Yang, Lu,et al."Two tandem multicomponent reactions for the synthesis of sequence-defined polymers".SCIENCE CHINA-CHEMISTRY 58.11(2015):1734-1740. |
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来源：化学研究所
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