Effects of rigid cores and flexible tails on the phase behaviors of polynorbornene-based mesogen-jacketed liquid crystalline polymers
文献类型:期刊论文
作者 | Zhang, Zhen-Yu; Wang, Qian; Hou, Ping-Ping; Shen, Zhihao; Fan, Xing-He |
刊名 | POLYMER CHEMISTRY
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出版日期 | 2015 |
卷号 | 6期号:44页码:7701-7710 |
英文摘要 | A new series of mesogen-jacketed liquid crystalline polymers (MJLCPs) with a polynorbornene main chain and different side groups were prepared by ring-opening metathesis polymerization. The liquid crystalline (LC) phase behaviors of these polymers were investigated by differential scanning calorimetry, polarized light microscopy, and wide-angle X-ray diffraction. Depending on the rigid side-chain core and peripheral alkyl chains, these polymers show different LC structures. The polymer with the terphenyl rigid side-chain core and relatively short alkyl tails is amorphous in the whole temperature range, while those with the same rigid side-chain core but longer alkyl tails exhibit columnar nematic (Col(n)) phases. Polymers with a longer rigid side-chain core and relatively long alkyl tails develop into smectic A (SmA) phases. In addition, the LC polymers obtained in this study display LC phases in wide temperature ranges. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2015-12-22 |
源URL | [http://ir.iccas.ac.cn/handle/121111/29202] ![]() |
专题 | 化学研究所_高分子物理与化学实验室 |
作者单位 | Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci,Minist Educ, Key Lab Polymer Chem & Phys,Ctr Soft Matter Sci &, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Zhen-Yu,Wang, Qian,Hou, Ping-Ping,et al. Effects of rigid cores and flexible tails on the phase behaviors of polynorbornene-based mesogen-jacketed liquid crystalline polymers[J]. POLYMER CHEMISTRY,2015,6(44):7701-7710. |
APA | Zhang, Zhen-Yu,Wang, Qian,Hou, Ping-Ping,Shen, Zhihao,&Fan, Xing-He.(2015).Effects of rigid cores and flexible tails on the phase behaviors of polynorbornene-based mesogen-jacketed liquid crystalline polymers.POLYMER CHEMISTRY,6(44),7701-7710. |
MLA | Zhang, Zhen-Yu,et al."Effects of rigid cores and flexible tails on the phase behaviors of polynorbornene-based mesogen-jacketed liquid crystalline polymers".POLYMER CHEMISTRY 6.44(2015):7701-7710. |
入库方式: OAI收割
来源:化学研究所
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