中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Syntheses and luminescence properties of EU(III) complexes with benzoic acid carboxymethyl ester derivatives

文献类型:期刊论文

作者Xi, Peng1,2; Xia, Haiying1; Zhao, Fulai1; Chen, Bowen1
刊名MATERIALS LETTERS
出版日期2015-12-01
卷号160页码:463-467
关键词Europium Benzoic acid Luminescence Thermal properties Crystal structure
英文摘要Benzoic acid carboxymethyl ester derivatives (BACED) with different substituents and their Eu(III) complexes (Eu(BACED)(3)(H2O)(2)) were synthesized, BACED being a bidentate ligand. The as-prepared complexes showed cloud flake aggregation structures with size in the range of 50-60 nm. The luminescence spectra of the complexes indicated effective energy transfer from BACED to Eu3+. Three distinct peaks were observed in the excitation spectra of the Eu(III) complexes containing BACED and the as-prepared complexes exhibited effective emission when the wavelengths corresponding to these peaks were used as the excitation wavelengths. The longest luminescence lifetime of the as-prepared complexes was 1099.25 mu s and the best luminescent quantum efficiency was 59.21%. These results indicate that the Eu(III) complexes with BACED have excellent potential for use as luminescent materials. (C) 2015 Elsevier B.V. All rights reserved.
收录类别SCI
语种英语
公开日期2015-12-22
源URL[http://ir.iccas.ac.cn/handle/121111/29247]  
专题化学研究所_高分子物理与化学实验室
作者单位1.Tianjin Polytech Univ, Tianjin Municipal Key Lab Fiber Modificat & Funct, Tianjin 300387, Peoples R China
2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Xi, Peng,Xia, Haiying,Zhao, Fulai,et al. Syntheses and luminescence properties of EU(III) complexes with benzoic acid carboxymethyl ester derivatives[J]. MATERIALS LETTERS,2015,160:463-467.
APA Xi, Peng,Xia, Haiying,Zhao, Fulai,&Chen, Bowen.(2015).Syntheses and luminescence properties of EU(III) complexes with benzoic acid carboxymethyl ester derivatives.MATERIALS LETTERS,160,463-467.
MLA Xi, Peng,et al."Syntheses and luminescence properties of EU(III) complexes with benzoic acid carboxymethyl ester derivatives".MATERIALS LETTERS 160(2015):463-467.

入库方式: OAI收割

来源:化学研究所

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