Syntheses and luminescence properties of EU(III) complexes with benzoic acid carboxymethyl ester derivatives
文献类型:期刊论文
作者 | Xi, Peng1,2; Xia, Haiying1; Zhao, Fulai1; Chen, Bowen1 |
刊名 | MATERIALS LETTERS
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出版日期 | 2015-12-01 |
卷号 | 160页码:463-467 |
关键词 | Europium Benzoic acid Luminescence Thermal properties Crystal structure |
英文摘要 | Benzoic acid carboxymethyl ester derivatives (BACED) with different substituents and their Eu(III) complexes (Eu(BACED)(3)(H2O)(2)) were synthesized, BACED being a bidentate ligand. The as-prepared complexes showed cloud flake aggregation structures with size in the range of 50-60 nm. The luminescence spectra of the complexes indicated effective energy transfer from BACED to Eu3+. Three distinct peaks were observed in the excitation spectra of the Eu(III) complexes containing BACED and the as-prepared complexes exhibited effective emission when the wavelengths corresponding to these peaks were used as the excitation wavelengths. The longest luminescence lifetime of the as-prepared complexes was 1099.25 mu s and the best luminescent quantum efficiency was 59.21%. These results indicate that the Eu(III) complexes with BACED have excellent potential for use as luminescent materials. (C) 2015 Elsevier B.V. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2015-12-22 |
源URL | [http://ir.iccas.ac.cn/handle/121111/29247] ![]() |
专题 | 化学研究所_高分子物理与化学实验室 |
作者单位 | 1.Tianjin Polytech Univ, Tianjin Municipal Key Lab Fiber Modificat & Funct, Tianjin 300387, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Xi, Peng,Xia, Haiying,Zhao, Fulai,et al. Syntheses and luminescence properties of EU(III) complexes with benzoic acid carboxymethyl ester derivatives[J]. MATERIALS LETTERS,2015,160:463-467. |
APA | Xi, Peng,Xia, Haiying,Zhao, Fulai,&Chen, Bowen.(2015).Syntheses and luminescence properties of EU(III) complexes with benzoic acid carboxymethyl ester derivatives.MATERIALS LETTERS,160,463-467. |
MLA | Xi, Peng,et al."Syntheses and luminescence properties of EU(III) complexes with benzoic acid carboxymethyl ester derivatives".MATERIALS LETTERS 160(2015):463-467. |
入库方式: OAI收割
来源:化学研究所
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