Preparation of graphene/poly(p-phenylenebenzobisoxazole) composite fibers based on simultaneous zwitterion coating and chemical reduction of graphene oxide at room temperature
文献类型：期刊论文
| 作者 | Guo, Jianqiang1,2; Guan, Guohu1; Zhou, Wen3; Li, Chuncheng1; Xiao, Yaonan1; Zhu, Wenxiang1; Zheng, Liuchun1 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:108页码:88646-88654 |
| 英文摘要 | Zwitterion-coated reduced graphene oxide (rGO) was used in fabricating graphene/PBO composite fibers via in situ polymerization. The zwitterionic 1 : 1 adducts were formed by two monomers of PBO and they could be crystallized using rGO sheets as templates. Covalent bonds could be formed between GO and 4,6-diaminoresorcinol dihydrochloride (DAR center dot 2HCl, a monomer for PBO) with GO being reduced simultaneously at room temperature. The structure of rGO sheets was well characterized and a mechanism including nucleophilic addition and E1 dehydration was proposed. Zwitterions could precipitate out from water rapidly and yet dissolve in PPA easily. Thereby, rGO sheets could be homogeneously dispersed in the PBO matrix as zwitterions dissolve and polymerize. By adjusting the feeding of zwitterion-coated rGO sheets, various composites with 0.1-3.0 wt% GO sheets incorporated were obtained. With very low rGO sheet content, both the mechanical properties and thermal stability of rGO/PBO fibers increased remarkably. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-12-22 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/29159]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Inst Chem Def, Beijing 102205, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Jianqiang,Guan, Guohu,Zhou, Wen,et al. Preparation of graphene/poly(p-phenylenebenzobisoxazole) composite fibers based on simultaneous zwitterion coating and chemical reduction of graphene oxide at room temperature[J]. RSC ADVANCES,2015,5(108):88646-88654. |
| APA | Guo, Jianqiang.,Guan, Guohu.,Zhou, Wen.,Li, Chuncheng.,Xiao, Yaonan.,...&Zheng, Liuchun.(2015).Preparation of graphene/poly(p-phenylenebenzobisoxazole) composite fibers based on simultaneous zwitterion coating and chemical reduction of graphene oxide at room temperature.RSC ADVANCES,5(108),88646-88654. |
| MLA | Guo, Jianqiang,et al."Preparation of graphene/poly(p-phenylenebenzobisoxazole) composite fibers based on simultaneous zwitterion coating and chemical reduction of graphene oxide at room temperature".RSC ADVANCES 5.108(2015):88646-88654. |
入库方式： OAI收割
来源：化学研究所
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