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Synthesis and electrochemical performance of Li2FeSiO4/C as cathode material for lithium batteries
文献类型:期刊论文
作者 | Huang, Xiaobing1,2; Li, Xing3; Wang, Haiyan4; Pan, Zhonglai; Qu, Meizhen1; Yu, Zuolong1 |
刊名 | SOLID STATE IONICS
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出版日期 | 2010-10-07 |
卷号 | 181期号:31-32页码:1451-1455 |
关键词 | Lithium ion battery Solid-state reaction Li2FeSiO4/C Pitch |
英文摘要 | Li2FeSiO4/C cathode material was synthesized by a traditional solid-state reaction method with Li2CO3, FeC2O4 center dot 2H(2)O, nano SiO2 as starting materials and pitch as the carbon source. For comparison, the Li2FeSiO4/C with glucose as the carbon source and the pristine Li2FeSiO4 were also prepared. The as-prepared materials were characterized by X-ray diffraction, scanning electron microscopy, elementary analyzer, BET specific surface area, galvanostatic charge-discharge test and AC impedance spectroscopy. The results demonstrated that the Li2FeSiO4/C composites showed better electrochemical properties compared with the pristine Li2FeSiO4. Surprisingly, the Li2FeSiO4/C with pitch as carbon source exhibited the best electrochemical properties among the three samples, it delivered a specific discharge capacity of 139 mAh g(-1), 127 mAh g(-1), 118 mAh g(-1) and 103 mAh g(-1) at 0.2 C, 0.5 C, 1 C and 2 C, respectively. After 100 cycles at the rate of 1 C, the discharge capacity remained 93.6% of its initial value. (C) 2010 Elsevier B.V. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Physical ; Physics, Condensed Matter |
研究领域[WOS] | Chemistry ; Physics |
关键词[WOS] | LIFEPO4/C COMPOSITE CATHODE ; ION BATTERIES ; SURFACE ; PRECURSORS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000284188400010 |
公开日期 | 2015-12-24 |
源URL | [http://ir.ioe.ac.cn/handle/181551/3379] ![]() |
专题 | 光电技术研究所_光电技术研究所被WoS收录文章 |
作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Inst Opt & Elect, Chengdu 610041, Peoples R China 4.Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China |
推荐引用方式 GB/T 7714 | Huang, Xiaobing,Li, Xing,Wang, Haiyan,et al. Synthesis and electrochemical performance of Li2FeSiO4/C as cathode material for lithium batteries[J]. SOLID STATE IONICS,2010,181(31-32):1451-1455. |
APA | Huang, Xiaobing,Li, Xing,Wang, Haiyan,Pan, Zhonglai,Qu, Meizhen,&Yu, Zuolong.(2010).Synthesis and electrochemical performance of Li2FeSiO4/C as cathode material for lithium batteries.SOLID STATE IONICS,181(31-32),1451-1455. |
MLA | Huang, Xiaobing,et al."Synthesis and electrochemical performance of Li2FeSiO4/C as cathode material for lithium batteries".SOLID STATE IONICS 181.31-32(2010):1451-1455. |
入库方式: OAI收割
来源:光电技术研究所
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