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Synthesis, characterization, and luminescent properties of a red-emitting Europium complex (EI CONFERENCE) 会议论文  OAI收割
1st International Conference on Energy and Environmental Protection, ICEEP 2012, June 23, 2012 - June 24, 2012, Hohhot, China
作者:  
Li B.;  Zhang L.;  Zhang L.;  Li B.;  Li B.
收藏  |  浏览/下载:71/0  |  提交时间:2013/03/25
a fluorine functionalized 1  10-phenanthroline ligand  3-ethyl-2-(2- fluorophenyl) imidazo[4  5-f]1  10-phenanthroline(EFPIP) and the corresponding red-emitting Eu(III) complex Eu(DBM)3(EFPIP) (DBM = dibenzoylmethanate) was synthesized and the photophysical properties and electroluminescent(EL) performances were researched. When Eu(DBM) 3(EFPIP) was used as emitting material in organic devices  the maximum efficiency and luminance of red emission achieved from the EL device with the configuration of ITO/m-MTDATA (30 nm)/NPB (20 nm)/x wt% Eu(DBM) 3(EFPIP) doped in CBP (30 nm)/Bphen (20 nm)/Alq3 (20 nm)/LiF (0.8 nm)/Al were 3.6 cd/A and 563 cd/m2  respectively. Compared with the previously reported devices based on methyl or chlorine substitute Eu(III) complexes  the EL performances of the device using Eu(DBM)3(EFPIP) as an emitter was significantly enhanced due to the introduction of fluorine. (2012) Trans Tech Publications  Switzerland.