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Synthesis, characterization, and ethylene polymerization behaviors of late-transition metal complexes coordinated with chlorinated bis(arylimino)pyridine ligand 期刊论文  OAI收割
polymer, 2014, 卷号: 55, 期号: 18, 页码: 4611-4618
Liu, Heng; Wang, Feng; Liu, Li; Jai,Xiang-Yu; Zheng,Wenjie; Guo,Jun; Zhang,Chun-Yu; Bai,Chen-Xi; Hu,Yan-Ming; Zhang,Xue-Quan
收藏  |  浏览/下载:32/0  |  提交时间:2015/10/20
A series of late-transition metal complexes supported with chlorinated bis(arylimino)pyridine ligands [2  Ar = 2  Ar = 2  Ar = 2  Ar = 4-Cl-2  Ar = 4-Br-2  6-(ArN=CCl)(2)C5H3N]MtCl(2) (Ar = 2  6-(Pr2C6H3)-Pr-i  6-Et2C6H3  6-Me2C6H3  6-Me2C6H2  6-Me2C6H2  4  Mt = Fe (1b)  Mt = Co (1c)  Mt = Fe (1d)  Mt = Fe (1e)  Mt = Fe (1f)  6-Me3C6H2  Co (2b)  Ni (3c)  Co (2d)  Co (2e)  Co (2f)) were synthesized. At the presence of methylaluminoxane (MAO)  Mt = Fe (1a)  Fe(II)- and Co(II)- based complexes were highly active towards ethylene polymerization  Co (2a)  affording polymers with bimodal and unimodal molar. mass distributions  Ni (3a)  respectively  while the Ni(II)-based complexes gave no polymer products. Moreover  the obtained polyethylenes were predominately saturated and vinyl-terminated for Fe(II)- and Co(II)-based complexes  respectively. Changing the ligand environment  polymerization parameters also posed a great influence on the catalytic activities and the properties of the resulting polymers. (C) 2014 Elsevier Ltd. All rights reserved.  
乙烯淤浆聚合用茂金属催化剂的开发研究 学位论文  OAI收割
理学博士: 中国科学院研究生院, 2004
朱博超
收藏  |  浏览/下载:43/0  |  提交时间:2014/04/14
Preparation and application of a novel core-shell-particle-supported zirconocene catalyst 期刊论文  OAI收割
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2001, 卷号: 39, 期号: 13, 页码: 2085-2092
作者:  
Liu, CB;  Tang, T;  Huang, BT
  |  收藏  |  浏览/下载:14/0  |  提交时间:2019/04/09