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Influence of sensitizer concentration on the upconversion luminescence of NaYF4: Yb3+, Er3+ nanoparticles (EI CONFERENCE) 会议论文  OAI收割
2012 2nd International Conference on Machinery, Materials Science and Engineering Applications, MMSE 2012, June 16, 2012 - June 17, 2012, Wuhan, China
作者:  
Zhao J.;  Zhao Y.;  Zhao Y.;  Zhao Y.
收藏  |  浏览/下载:24/0  |  提交时间:2013/03/25
A series of NaYF4: Yb3+  Er3+ nanoparticles with different doping concentration were successfully prepared by the combination of coprecipitation and hydrothermal methods using sodium citrate as chelator. Upconversion luminescence can be observed in all of the samples at room temperature. Fixed the Er3+ concentration with 1 mol% unchanged  the effect of the Yb3+ concentration on the upconversion luminescence of NaYF4: Yb3+  Er3+ samples were studied when the doped Yb3+ concentrations were 0 mol%  1 mol%  2 mol%  5 mol%  10 mol% and 20 mol%  respectively. As increasing the Yb 3+ concentration  the total intensity of the upconversion luminescence of the samples is increasing while the ratio of red to green emission increases firstly and then decreases. The maximum ratio value is 22.1 when the Yb3+ concentration is 10 mol%. It is found that the cross relaxation and cooperative sensitization effect are the reasons for the phenomenon above. (2012) Trans Tech Publications.