机构

• 长春光学精密机械与物... [1]

采集方式

• OAI收割 [1]

内容类型

• 会议论文 [1]

发表日期

• 2011 [1]

学科主题

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浏览/检索结果: 共1条，第1-1条 帮助 限定条件 内容类型：会议论文     条数/页： 5101520253035404550556065707580859095100 排序方式： 请选择提交时间升序提交时间降序发表日期升序发表日期降序题名升序题名降序作者升序作者降序 Energy transfer in Y3Al5O12:Ce 3, Pr3+ and CaMoO4:Sm3, Eu 3 phosphors (EI CONFERENCE) 会议论文  OAI收割 作者:  Wang L.;  Wang X.-J.;  Zhang X.;  Zhang X.;  Zhang X. 收藏  |  浏览/下载：24/0  |  提交时间：2013/03/25 Non-radiative energy transfers (ET) from Ce3 to Pr3+ in Y3Al5O12:Ce3  Pr3+ and from Sm3 to Eu3 in CaMoO4:Sm3  Eu3 are studied based on photoluminescence spectroscopy and fluorescence decay patterns. The result indicates an electric dipoledipole interaction that governs ET in the LED phosphors. For Ce3 concentration of 0.01 in YAG:Ce3  Pr3+  the rate constant and critical distance are evaluated to be 4.510-36 cm 6 s-1 and 0.81 nm  respectively. An increase in the red emission line of Pr3+ relative to the yellow emission band of Ce 3  on increasing Ce3 concentration is observed. This behavior is attributed to the increase of spectral overlap integrals between Ce3 emission and Pr3+ excitation due to the fact that the yellow band shifts to the red spectral side with increasing Ce3 concentration. In CaMoO4:Sm3  Eu3  Sm 3Eu3 transfer occurs from 4G5/2 of Sm3 to 5D0 of Eu3. The rate constant of 8.510-40 cm6 s-1 and the critical transfer distance of 0.89 nm are evaluated. 2010 Elsevier B.V. All rights reserved.