Rhodium-Catalyzed Asymmetric Arylation of beta,gamma-Unsaturated alpha-Ketoamides for the Construction of Nonracemic gamma,gamma-Diarylcarbonyl Compounds
文献类型：期刊论文
| 作者 | Wang, Juanjuan ; Wang, Min ; Cao, Peng ; Jiang, Liyin ; Chen, Guihua ; Liao, Jian |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2014 |
| 卷号 | 53期号:26页码:6673-6677 |
| 关键词 | asymmetric synthesis enantioselectivity homogeneous catalysis rhodium S P ligands |
| 产权排序 | 3 |
| 通讯作者 | Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China. |
| 合作状况 | 其它 |
| 英文摘要 | A highly regio- and enantioselective rhodium-catalyzed 1,4-addition of arylboronic acids to beta,gamma-unsaturated alpha-ketoamides using a simple new chiral sulfinylphosphine ligand is described. This transformation provides an attractive approach to construct chiral nonracemic gamma,gamma-diarylsubstituted carbonyl compounds, as exemplified in the concise syntheses of sertraline and tetrahydroquinoline-2-carboxylamide. |
| 学科主题 | Chemistry, Multidisciplinary |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-02-26 |
| 源URL | [http://210.75.237.14/handle/351003/26680]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Wang, Juanjuan,Wang, Min,Cao, Peng,et al. Rhodium-Catalyzed Asymmetric Arylation of beta,gamma-Unsaturated alpha-Ketoamides for the Construction of Nonracemic gamma,gamma-Diarylcarbonyl Compounds[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(26):6673-6677. |
| APA | Wang, Juanjuan,Wang, Min,Cao, Peng,Jiang, Liyin,Chen, Guihua,&Liao, Jian.(2014).Rhodium-Catalyzed Asymmetric Arylation of beta,gamma-Unsaturated alpha-Ketoamides for the Construction of Nonracemic gamma,gamma-Diarylcarbonyl Compounds.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,53(26),6673-6677. |
| MLA | Wang, Juanjuan,et al."Rhodium-Catalyzed Asymmetric Arylation of beta,gamma-Unsaturated alpha-Ketoamides for the Construction of Nonracemic gamma,gamma-Diarylcarbonyl Compounds".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.26(2014):6673-6677. |
入库方式： OAI收割
来源：成都生物研究所
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