Octacoordinate Metal Carbonyls of Lanthanum and Cerium: Experimental Observation and Theoretical Calculation
文献类型：期刊论文
| 作者 | Xie, Hua1; Wang, Jie2; Qin, Zhengbo1; Shi, Lei1; Tang, Zichao1; Xing, Xiaopeng2 |
| 刊名 | journal of physical chemistry a
 |
| 出版日期 | 2014-10-09 |
| 卷号 | 118期号:40页码:9380-9385 |
| 通讯作者 | 唐紫超 ; xiaopengxing |
| 英文摘要 | the octacoordinate metal carbonyls la(co)(8)(+) and ce(co)(8)(+) were observed in laser vaporization of la and ce in pure co gas. the peak intensities in the mass spectra, the infrared photodissociation spectra, and the theoretical calculations indicate that all co ligands in these two complexes are bonded with the central metal atoms. the co stretching frequencies in la(co)(8)(+) and ce(co)(8)(+) are determined to be 2110 and 2108 cm(-1), respectively. theoretical studies indicate that the most stable structures for la(co)(8)(+) and ce(co)(8)(+) are an oh geometry at its triplet state and a slightly distorted oh geometry at its quartet state, respectively. these two complexes represent new octacoordinate metal carbonyls after previously determined u(co)(8)(+) and y(co)(8)(+). |
| 学科主题 | 物理化学 |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | gas-phase ; infrared-spectroscopy ; cluster cations ; solid argon ; complexes ; molecules ; spectra ; yttrium ; atoms ; scandium |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000343016900010 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144462]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xie, Hua,Wang, Jie,Qin, Zhengbo,et al. Octacoordinate Metal Carbonyls of Lanthanum and Cerium: Experimental Observation and Theoretical Calculation[J]. journal of physical chemistry a,2014,118(40):9380-9385. |
| APA | Xie, Hua,Wang, Jie,Qin, Zhengbo,Shi, Lei,Tang, Zichao,&Xing, Xiaopeng.(2014).Octacoordinate Metal Carbonyls of Lanthanum and Cerium: Experimental Observation and Theoretical Calculation.journal of physical chemistry a,118(40),9380-9385. |
| MLA | Xie, Hua,et al."Octacoordinate Metal Carbonyls of Lanthanum and Cerium: Experimental Observation and Theoretical Calculation".journal of physical chemistry a 118.40(2014):9380-9385. |
入库方式： OAI收割
来源：大连化学物理研究所
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