On the photoelectron velocity-map imaging of lutetium monoxide anion LuO-
文献类型：期刊论文
| 作者 | Liu, Zhiling1; Xie, Hua1; Li, Quanjiang2,3; Qin, Zhengbo1; Cong, Ran1; Wu, Xia1; Tang, Zichao1; Fan, Hongjun1 |
| 刊名 | journal of chemical physics
 |
| 出版日期 | 2014-01-21 |
| 卷号 | 140期号:3 |
| 英文摘要 | we report a combined photoelectron velocity-map imaging spectroscopy and density functional theory investigation on lutetium monoxide anion. transition between the x-1 sigma(+) anion electronic ground state and the neutral x-2 sigma(+) electronic ground state is observed. vibrationally resolved spectra were obtained at four different photon energies, providing a wealth of spectroscopic information for the electronic ground states of the anionic lutetium monoxide and corresponding neutral species. franck-condon simulations of the ground-state transition are performed to assign vibrational structure in the spectra and to assist in identifying the observed spectral bands. the electronic ground state of luo- is found to have a vibrational frequency of 743 +/- 10 cm(-1) and an equilibrium bond length of 1.841 angstrom. the electron affinity of luo is measured to be 1.624 +/- 0.002 ev. the fundamental frequency of ground-state luo is estimated to be 839 +/- 10 cm(-1). (c) 2014 aip publishing llc. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | main-group thermochemistry ; rare-earth-elements ; noncovalent interactions ; lanthanide oxides ; molecular-oxygen ; basis-sets ; pseudopotentials ; transition ; kinetics ; spectrum |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000330614400030 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145621]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Dalian Univ Technol, Sch Phys & Optoelect Technol, Dalian 116024, Peoples R China 3.Dalian Univ Technol, Coll Adv Sci & Technol, Dalian 116024, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Zhiling,Xie, Hua,Li, Quanjiang,et al. On the photoelectron velocity-map imaging of lutetium monoxide anion LuO-[J]. journal of chemical physics,2014,140(3). |
| APA | Liu, Zhiling.,Xie, Hua.,Li, Quanjiang.,Qin, Zhengbo.,Cong, Ran.,...&Fan, Hongjun.(2014).On the photoelectron velocity-map imaging of lutetium monoxide anion LuO-.journal of chemical physics,140(3). |
| MLA | Liu, Zhiling,et al."On the photoelectron velocity-map imaging of lutetium monoxide anion LuO-".journal of chemical physics 140.3(2014). |
入库方式： OAI收割
来源：大连化学物理研究所
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