Vibrationally Resolved Photoelectron Imaging of Au3H-
文献类型：期刊论文
| 作者 | Liu, Zhiling; Qin, Zhengbo; Wu, Xia; Xie, Hua; Cong, Ran; Tang, Zichao |
| 刊名 | journal of physical chemistry a
 |
| 出版日期 | 2014-02-13 |
| 卷号 | 118期号:6页码:1031-1037 |
| 英文摘要 | we report a combined photoelectron velocity map imaging spectroscopy and density functional theory investigation on the au3h- anion. transition between the anionic electronic ground state and the neutral electronic ground state is revealed. vibrationally resolved spectra were recorded at two different photon energies, providing a wealth of spectroscopic information for the electronic ground state of the au3h. franck-condon simulations of the ground-state transition are carried out to assist in the assignment of the vibrationally resolved spectra. the electron affinity and vertical detachment energy of au3h are measured to be 2.548 +/- 0.001 and 2.570 +/- 0.001 ev, respectively. three stretching vibrational modes are determined to be activated upon photodetachment, with the frequencies of 2100 +/- 100, 177 +/- 10, and 96 +/- 10 cm(-1). |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | matrix infrared-spectra ; transform emission-spectroscopy ; coinage metal-hydrides ; dft calculations ; gold clusters ; theoretical chemistry ; solid hydrogen ; mp2 energy ; basis-sets ; mh4-m |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000331493500009 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145741]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Zhiling,Qin, Zhengbo,Wu, Xia,et al. Vibrationally Resolved Photoelectron Imaging of Au3H-[J]. journal of physical chemistry a,2014,118(6):1031-1037. |
| APA | Liu, Zhiling,Qin, Zhengbo,Wu, Xia,Xie, Hua,Cong, Ran,&Tang, Zichao.(2014).Vibrationally Resolved Photoelectron Imaging of Au3H-.journal of physical chemistry a,118(6),1031-1037. |
| MLA | Liu, Zhiling,et al."Vibrationally Resolved Photoelectron Imaging of Au3H-".journal of physical chemistry a 118.6(2014):1031-1037. |
入库方式： OAI收割
来源：大连化学物理研究所
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