Infrared photodissociation spectroscopy of MO(CO)(5)(+) (M = Sc, Y, La and Ce) in the gas phase
文献类型：期刊论文
| 作者 | Xie, Hua1; Liu, Zhiling1; Xing, Xiaopeng2; Tang, Zichao1 |
| 刊名 | chemical physics letters
 |
| 出版日期 | 2015-05-16 |
| 卷号 | 628页码:66-70 |
| 英文摘要 | the mo(co)(5)(+)(m = sc, y, la and ce) complexes are generated and analyzed using an infrared photodissociation spectrometer. their c-o stretching frequencies are determined to be 2210 cm(-1), 2206 cm(-1), 2198 cm(-1) and 2196 cm(-1) for m = sc, y, la and ce, respectively. the simulated spectra from dft calculations are compared with the experimental results, indicating mo(co)(5)(+) (m = sc, y, la and ce) are or very close to pentagonal pyramidal structures with c-5v symmetry. the comparisons of these complexes with other metal carbonyls help to elucidate the characteristics of co coordination in various metal species. (c) 2015 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | octacoordinate metal-carbonyls ; solid argon ; reaction-products ; molecular-oxygen ; multiple ar ; xe atoms ; spectra ; coordination ; transition ; cations |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000353975300012 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146229]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xie, Hua,Liu, Zhiling,Xing, Xiaopeng,et al. Infrared photodissociation spectroscopy of MO(CO)(5)(+) (M = Sc, Y, La and Ce) in the gas phase[J]. chemical physics letters,2015,628:66-70. |
| APA | Xie, Hua,Liu, Zhiling,Xing, Xiaopeng,&Tang, Zichao.(2015).Infrared photodissociation spectroscopy of MO(CO)(5)(+) (M = Sc, Y, La and Ce) in the gas phase.chemical physics letters,628,66-70. |
| MLA | Xie, Hua,et al."Infrared photodissociation spectroscopy of MO(CO)(5)(+) (M = Sc, Y, La and Ce) in the gas phase".chemical physics letters 628(2015):66-70. |
入库方式： OAI收割
来源：大连化学物理研究所
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