Diaryliodoniums by Rhodium(III)-Catalyzed C-H Activation: Mild Synthesis and Diversified Functionalizations
文献类型：期刊论文
| 作者 | Xie, Fang1; Zhang, Zhipeng1; Yu, Xinzhang1,2; Tang, Guodong1; Li, Xingwei1 |
| 刊名 | angewandte chemie-international edition
 |
| 出版日期 | 2015-06-15 |
| 卷号 | 54期号:25页码:7405-7409 |
| 关键词 | arenes C-H activation copper hypervalent compounds rhodium |
| 英文摘要 | diaryliodonium salts play an increasingly important role as an aryl source. reported is the first synthesis of diaryliodoniums by rhodium(iii)-catalyzed c-h hyperiodination of electron-poor arenes under chelation assistance. this c-i coupling reaction occurred at room temperature with high regio-selectivity and functional-group compatibility. subsequent diversified nucleophilic functionalization of a diarylio-donium allowed facile construction of c-c, c-n, c-o, c-s, c-p and c-br bonds, and in all cases the initial functionalization occurred at the arene containing the chelating-group. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | one-pot synthesis ; room-temperature ; unsymmetrical lambda(3)-iodanes ; catalyzed fluorination ; chelation-assistance ; polyvalent iodine ; arylboronic acids ; coupling reaction ; bond activation ; iodonium salts |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000356390300035 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146336]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Taiyuan Inst Technol, Dept Chem & Chem Engn, Taiyuan 030008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xie, Fang,Zhang, Zhipeng,Yu, Xinzhang,et al. Diaryliodoniums by Rhodium(III)-Catalyzed C-H Activation: Mild Synthesis and Diversified Functionalizations[J]. angewandte chemie-international edition,2015,54(25):7405-7409. |
| APA | Xie, Fang,Zhang, Zhipeng,Yu, Xinzhang,Tang, Guodong,&Li, Xingwei.(2015).Diaryliodoniums by Rhodium(III)-Catalyzed C-H Activation: Mild Synthesis and Diversified Functionalizations.angewandte chemie-international edition,54(25),7405-7409. |
| MLA | Xie, Fang,et al."Diaryliodoniums by Rhodium(III)-Catalyzed C-H Activation: Mild Synthesis and Diversified Functionalizations".angewandte chemie-international edition 54.25(2015):7405-7409. |
入库方式： OAI收割
来源：大连化学物理研究所
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