Biopolyol preparation from liquefaction of grape seeds
文献类型:期刊论文
作者 | Shao, Qiang1,2; Li, Hong-Qiang1; Huang, Chong-Pin2; Xu, Jian1 |
刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
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出版日期 | 2016-09-10 |
卷号 | 133期号:34页码:1-5 |
关键词 | biopolymers & renewable polymers catalysts cellulose and other wood products |
ISSN号 | 0021-8995 |
英文摘要 | The feasibility of liquefying grape seeds (GS) in the blended solvents of PEG 400 and glycerol for the production of biopolyol was investigated. Different liquefaction conditions have great influences on the residue ratio of GS. The influences of the liquefaction condition such as temperature, time, catalyst percentage, and liquid-solid ratio on the residue ratio were discussed. The optimal conditions obtained were 180 degrees C, 120 min, catalyst percentage (percentage of solvent mass) of 3.5%, and liquid-solid ratio of 4. The FTIR showed that the lignin, cellulose, and hemicellulose in the GS were effectively decomposed in the liquefaction process. The characteristic parameters of the biopolyol were as follows: hydroxyl number of 397.46 mg KOH/g, acid number of 1.85 mg KOH/g, viscosity of 2960 mPas, weight-average molecular weight of 5.18 x 10(3) gmol(-1), and polydispersity of 3.64. These results suggest that the GS-based polyol was suitable for the production of polyurethane foams. (c) 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43835. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Polymer Science |
研究领域[WOS] | Polymer Science |
关键词[WOS] | BIODEGRADABLE POLYURETHANE FOAM ; LIGNOCELLULOSIC BIOMASS ; POLYHYDRIC ALCOHOLS ; CRUDE GLYCEROL ; WHEAT-STRAW ; CORN STOVER ; EXTRACTION ; PRODUCTS ; POLYOLS ; LIGNIN |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000378427300016 |
源URL | [http://ir.ipe.ac.cn/handle/122111/21181] ![]() |
专题 | 过程工程研究所_生化工程国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China 2.Beijing Univ Chem Technol, Changzhou Inst Adv Mat, Beijing 100029, Peoples R China |
推荐引用方式 GB/T 7714 | Shao, Qiang,Li, Hong-Qiang,Huang, Chong-Pin,et al. Biopolyol preparation from liquefaction of grape seeds[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2016,133(34):1-5. |
APA | Shao, Qiang,Li, Hong-Qiang,Huang, Chong-Pin,&Xu, Jian.(2016).Biopolyol preparation from liquefaction of grape seeds.JOURNAL OF APPLIED POLYMER SCIENCE,133(34),1-5. |
MLA | Shao, Qiang,et al."Biopolyol preparation from liquefaction of grape seeds".JOURNAL OF APPLIED POLYMER SCIENCE 133.34(2016):1-5. |
入库方式: OAI收割
来源:过程工程研究所
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