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A Cu/Pd Cooperative Catalysis for Enantioselective Allylboration of Alkenes
文献类型：期刊论文
| 作者 | Jia, Tao; Cao, Peng; Wang, Bing; Lou, Yazhou; Yin, Xuemei; Wang, Min; Liao, Jian |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2015 |
| 卷号 | 137期号:43页码:13760-13763 |
| 关键词 | CROSS-COUPLING REACTIONS SYNERGISTIC CATALYSIS ALLYLIC ALKYLATION 3-COMPONENT CARBOBORATION BIMETALLIC CATALYSIS ARYL BIS(PINACOLATO)DIBORON TRANSFORMATIONS HYDROBORATION CONSTRUCTION |
| 产权排序 | 1 |
| 通讯作者 | Liao, J (reprint author), Chinese Acad Sci, Nat Prod Res Ctr, Chengdu Inst Biol, Chengdu 610041, Peoples R China. |
| 合作状况 | 国内 |
| 英文摘要 | A cooperative Cu/Pd-catalyzed asymmetric three-component reaction of styrenes, B-2(pin)(2), and allyl carbonates was reported. This reaction, in the presence of chiral CuOAc/SOP and achiral Pd(dppf)Cl-2 catalysts, occurs smoothly with high enantioselectivities (up to 97% ee). The allylboration products, which contain alkene (or diene) unite and alkylboron group, are easily functionalized. The utility of this protocol was demonstrated through the synthesis of an antipsychotic drug, (-)-predamol. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| 源URL | [http://210.75.237.14/handle/351003/27559]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Jia, Tao,Cao, Peng,Wang, Bing,et al. A Cu/Pd Cooperative Catalysis for Enantioselective Allylboration of Alkenes[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2015,137(43):13760-13763. |
| APA | Jia, Tao.,Cao, Peng.,Wang, Bing.,Lou, Yazhou.,Yin, Xuemei.,...&Liao, Jian.(2015).A Cu/Pd Cooperative Catalysis for Enantioselective Allylboration of Alkenes.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,137(43),13760-13763. |
| MLA | Jia, Tao,et al."A Cu/Pd Cooperative Catalysis for Enantioselective Allylboration of Alkenes".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 137.43(2015):13760-13763. |
入库方式： OAI收割
来源：成都生物研究所
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