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Copper-Catalyzed Enantioselective 1,6-Boration of para-Quinone Methides and Efficient Transformation of gem-Diarylmethine Boronates to Triarylmethanes
文献类型：期刊论文
| 作者 | Lou, Yazhou; Cao, Peng; Jia, Tao; Zhang, Yongling; Wang, Min; Liao, Jian |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2015 |
| 卷号 | 54期号:41页码:12134-12138 |
| 关键词 | CROSS-COUPLING REACTIONS ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS ASYMMETRIC BETA-BORATION TERTIARY BORONIC ESTERS LITHIATION/BORYLATION-PROTODEBORONATION METHODOLOGY CONJUGATE ADDITIONS STEREOGENIC CENTERS CHIRAL SECONDARY 7-CYANO-7-ETHOXYCARBONYL-1,4-BENZOQUINONE METHIDE ANTIPROLIFERATIVE AGENTS |
| 产权排序 | 1 |
| 通讯作者 | Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Peoples R China. |
| 合作状况 | 国内 |
| 英文摘要 | Presented is the first enantioselective copper-catalyzed 1,6-conjugate addition of bis(pinacolato) diboron to para-quinone methides. The reaction proceeds with excellent yields and good to excellent enantioselectivities, and provides an attractive approach to the construction of optically active gem-diarylmehtine boronic esters. Additionally, the subsequent conversion of the derived potassium trifluoroborates into triarylmethanes with highly enantiospecificity was realized. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| 源URL | [http://210.75.237.14/handle/351003/27565]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Lou, Yazhou,Cao, Peng,Jia, Tao,et al. Copper-Catalyzed Enantioselective 1,6-Boration of para-Quinone Methides and Efficient Transformation of gem-Diarylmethine Boronates to Triarylmethanes[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2015,54(41):12134-12138. |
| APA | Lou, Yazhou,Cao, Peng,Jia, Tao,Zhang, Yongling,Wang, Min,&Liao, Jian.(2015).Copper-Catalyzed Enantioselective 1,6-Boration of para-Quinone Methides and Efficient Transformation of gem-Diarylmethine Boronates to Triarylmethanes.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,54(41),12134-12138. |
| MLA | Lou, Yazhou,et al."Copper-Catalyzed Enantioselective 1,6-Boration of para-Quinone Methides and Efficient Transformation of gem-Diarylmethine Boronates to Triarylmethanes".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 54.41(2015):12134-12138. |
入库方式： OAI收割
来源：成都生物研究所
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