Copper-Catalyzed Asymmetric Three-Component Borylstannation: Enantioselective Formation of C-Sn Bond
文献类型：期刊论文
| 作者 | Jia, Tao; Cao, Peng; Wang, Ding; Lou, Yazhou; Liao, Jian |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2015 |
| 卷号 | 21期号:13页码:4918-4922 |
| 关键词 | CROSS-COUPLING REACTIONS TERMINAL ALKENES COPPER(I)-CATALYZED REACTION PALLADIUM CATALYSIS DYNAMIC RESOLUTION ARYLBORONIC ACIDS BORONIC ESTERS ARYL HALIDES DIBORATION STANNANES |
| 产权排序 | 1 |
| 通讯作者 | Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Nat Prod Res Ctr, Chengdu 610041, Peoples R China. |
| 合作状况 | 国内 |
| 英文摘要 | In summary, a first copper-catalyzed synthesis of alpha-aryl-beta-borylstannane compounds was accomplished through three-component borylstannation of aryl-substituted alkenes. In the exploration of an asymmetric variant, chiral sulfinylphosphine ligands proved advantageous in controlling stereochemistry of B-Cu addition and in promoting transmetalation of enantioenriched alkyl-Cu species. The stereochemical outcome supported a sequential syn-borylcupration and configuration-retentive transmetalation mechanism. Moreover, alpha-chiral beta-borylstannanes were easily transformed into a diverse array of secondary alkylstannanes and triarylethane with high enantiomeric purity. The applications of chiral sulfinylphosphine ligands to other tandem Cu-B addition reactions are currently under investigation in our group. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://210.75.237.14/handle/351003/27593]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Jia, Tao,Cao, Peng,Wang, Ding,et al. Copper-Catalyzed Asymmetric Three-Component Borylstannation: Enantioselective Formation of C-Sn Bond[J]. CHEMISTRY-A EUROPEAN JOURNAL,2015,21(13):4918-4922. |
| APA | Jia, Tao,Cao, Peng,Wang, Ding,Lou, Yazhou,&Liao, Jian.(2015).Copper-Catalyzed Asymmetric Three-Component Borylstannation: Enantioselective Formation of C-Sn Bond.CHEMISTRY-A EUROPEAN JOURNAL,21(13),4918-4922. |
| MLA | Jia, Tao,et al."Copper-Catalyzed Asymmetric Three-Component Borylstannation: Enantioselective Formation of C-Sn Bond".CHEMISTRY-A EUROPEAN JOURNAL 21.13(2015):4918-4922. |
入库方式： OAI收割
来源：成都生物研究所
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