中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Highly efficient and selective removal of trace lead from aqueous solutions by hollow mesoporous silica loaded with molecularly imprinted polymers

文献类型:期刊论文

作者Zhang, Zulei1,2; Zhang, Xingdi1; Niu, Dechao1; Li, Yongsheng1; Shi, Jianlin1,3
刊名JOURNAL OF HAZARDOUS MATERIALS
出版日期2017-04-15
卷号328页码:160-169
关键词Hollow mesoporous silica Molecular imprinting Pb2+ Selectivity Real water sample
英文摘要A novel type of adsorbent for the selective recognition and adsorption of trace Pb2+ from aqueous solutions has been successfully constructed simply by grafting molecularly imprinted polymers (MIPs) onto hollow mesoporous silica (HMS). Attractively, the HMS loaded with MIPs (H-MIPs) exhibits a fast adsorption kinetics, marked adsorption capacity of 40.52 mg/g and extremely high selectivity toward Pb2+ over Cu2+, Zn2+, Co2+, Mn2+ and Ni2+, and the selectivity coefficients have been determined to be as high as 50. Moreover, such high adsorptive capability and selectivity were retained for at least 6 runs, indicating the stability and reusability of H-MIPs. Lead ion contaminants in real water samples were successfully concentrated and approximately 100% recovered using H-MIPs. Theoretical analysis shows that the adsorption process of H-MIPs follows the pseudo-second-order kinetic and Langmuir isotherm models. These demonstrate that H-MIPs are greatly potential for the rapid and highly efficient removal of trace Pb2+ ions in complicated matrices. (C) 2017 Published by Elsevier B.V.
WOS标题词Science & Technology ; Technology ; Life Sciences & Biomedicine
类目[WOS]Engineering, Environmental ; Engineering, Civil ; Environmental Sciences
研究领域[WOS]Engineering ; Environmental Sciences & Ecology
关键词[WOS]SOLID-PHASE EXTRACTION ; ADSORPTION PERFORMANCE ; FUNCTIONAL MONOMERS ; WATER SAMPLES ; PB(II) ; IONS ; CD(II) ; PRECONCENTRATION ; NANOPARTICLES ; CHEMISTRY
收录类别SCI
语种英语
WOS记录号WOS:000395228300018
源URL[http://ir.sic.ac.cn/handle/331005/23716]  
专题上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文
作者单位1.East China Univ Sci & Technol, Sch Mat Sci & Engn, Lab Low Dimens Mat Chem, Key Lab Ultrafine Mat Minist Educ, Shanghai 200237, Peoples R China
2.Jiaxing Univ, Sch Biol & Chem Engn, Jiaxing 314001, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Zulei,Zhang, Xingdi,Niu, Dechao,et al. Highly efficient and selective removal of trace lead from aqueous solutions by hollow mesoporous silica loaded with molecularly imprinted polymers[J]. JOURNAL OF HAZARDOUS MATERIALS,2017,328:160-169.
APA Zhang, Zulei,Zhang, Xingdi,Niu, Dechao,Li, Yongsheng,&Shi, Jianlin.(2017).Highly efficient and selective removal of trace lead from aqueous solutions by hollow mesoporous silica loaded with molecularly imprinted polymers.JOURNAL OF HAZARDOUS MATERIALS,328,160-169.
MLA Zhang, Zulei,et al."Highly efficient and selective removal of trace lead from aqueous solutions by hollow mesoporous silica loaded with molecularly imprinted polymers".JOURNAL OF HAZARDOUS MATERIALS 328(2017):160-169.

入库方式: OAI收割

来源:上海硅酸盐研究所

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