Process simulation of mineral carbonation of phosphogypsum with ammonia under increased CO2 pressure
文献类型：期刊论文
| 作者 | Bao, Weijun1,2; Zhao, Hongtao1,3,4; Li, Huiquan1,2,4; Li, Songgeng3,4; Lin, Weigang3,4 |
| 刊名 | JOURNAL OF CO2 UTILIZATION
 |
| 出版日期 | 2017 |
| 卷号 | 17页码:125-136 |
| 关键词 | Carbon dioxide Phosphogypsum Ammonia Mineral carbonation Process simulation |
| ISSN号 | 2212-9820 |
| 英文摘要 | The mineral carbonation of phosphogypsum offers many advantages in sequestering CO2, solving the pollution problem of phosphogypsum stacking, and manufacturing high value-added chemical products with low energy consumption and cost. Using the Aspen Plus process simulation software, this work simulates a novel process for the mineral carbonation of phosphogypsum with ammonia under increased CO2 pressure. This process is divided into five sections, namely, pre-carbonation, enhanced carbonation, flash separation, gas phase absorption, and (NH4)(2)SO4 fertilizer production. With its large-scale application, this new process allows the sensitivity analysis of many operation conditions, identifies the optimal conditions for reducing the ammonia and energy consumption of (NH4)(2)SO4 fertilizer production, and achieves a high carbonation conversion with a fast reaction rate. The optimal conditions (6 bar enhanced carbonation pressure, 1 bar flash pressure, 38 degrees C ammonia absorption solution temperature, 1.05 ammonia excess ratio, 1.024 CO2 excess ratio, and 0.94 mass ratio of water to gypsum) yield the highest carbonation conversion, ammonia utilization ratio, and enhanced carbonation temperature of 99.9%, 95.2%, and 138.5 degrees C, respectively, all of which can help achieve a fast carbonation reaction rate. (C) 2016 Elsevier Ltd. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Multidisciplinary ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Engineering |
| 关键词[WOS] | GAS DESULFURIZATION GYPSUM ; PURE CALCIUM-CARBONATE ; DIRECT AQUEOUS CARBONATION ; RED GYPSUM ; SEQUESTRATION ; PRECIPITATION ; CAPTURE ; SYSTEM ; EQUILIBRIA ; PRODUCTS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000393928500015 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/21948]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100080, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Bao, Weijun,Zhao, Hongtao,Li, Huiquan,et al. Process simulation of mineral carbonation of phosphogypsum with ammonia under increased CO2 pressure[J]. JOURNAL OF CO2 UTILIZATION,2017,17:125-136. |
| APA | Bao, Weijun,Zhao, Hongtao,Li, Huiquan,Li, Songgeng,&Lin, Weigang.(2017).Process simulation of mineral carbonation of phosphogypsum with ammonia under increased CO2 pressure.JOURNAL OF CO2 UTILIZATION,17,125-136. |
| MLA | Bao, Weijun,et al."Process simulation of mineral carbonation of phosphogypsum with ammonia under increased CO2 pressure".JOURNAL OF CO2 UTILIZATION 17(2017):125-136. |
入库方式： OAI收割
来源：过程工程研究所
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