Diastereoselective alpha-Hydroxylation of N-tert-Butanesulfinyl Imidates and N'-tert-Butanesulfinyl Amidines with Molecular Oxygen
文献类型：期刊论文
| 作者 | Ma, PJ (Ma, Peng-Ju); Liu, H (Liu, Hui); Xu, YJ (Xu, Yan-Jun); Aisa, HA (Aisa, Haji Akber) ; Lu, CD (Lu, Chong-Dao)
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| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2018 |
| 卷号 | 20期号:4页码:1236-1239 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.8b00178 |
| 英文摘要 | Diastereoselective alpha-hydroxylation using molecular oxygen has been achieved with chiral alpha-alkyl N-tert-butanesulfinyl imidates and alpha-aryl N'-tert-butanesulfinyl amidines. The aza-enolates generated from deprotonation of imidates/amidines can be intercepted by O-2 with excellent diastereocontrol and subsequently transformed into alpha-hydroxylation products in the presence of the reductant trimethyl phosphite. |
| WOS记录号 | WOS:000426013600085 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/5238]  |
| 专题 | 新疆理化技术研究所_省部共建新疆特有药用资源利用重点实验室 新疆理化技术研究所_资源化学研究室 |
| 通讯作者 | Lu, CD (Lu, Chong-Dao) |
| 作者单位 | 1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Plant Resources & Chem Arid Zones, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, PJ ,Liu, H ,Xu, YJ ,et al. Diastereoselective alpha-Hydroxylation of N-tert-Butanesulfinyl Imidates and N'-tert-Butanesulfinyl Amidines with Molecular Oxygen[J]. ORGANIC LETTERS,2018,20(4):1236-1239. |
| APA | Ma, PJ ,Liu, H ,Xu, YJ ,Aisa, HA ,&Lu, CD .(2018).Diastereoselective alpha-Hydroxylation of N-tert-Butanesulfinyl Imidates and N'-tert-Butanesulfinyl Amidines with Molecular Oxygen.ORGANIC LETTERS,20(4),1236-1239. |
| MLA | Ma, PJ ,et al."Diastereoselective alpha-Hydroxylation of N-tert-Butanesulfinyl Imidates and N'-tert-Butanesulfinyl Amidines with Molecular Oxygen".ORGANIC LETTERS 20.4(2018):1236-1239. |
入库方式： OAI收割
来源：新疆理化技术研究所
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