Tetraphenylcyclopentadiene Derivatives: Aggregation-Induced Emission, Adjustable Luminescence from Green to Blue, Efficient Undoped OLED Performance and Good Mechanochromic Properties
文献类型：期刊论文
| 作者 | Ruan, Zhijun1; Li, Le2; Wang, Can3; Xie, Yujun1; Hu, Quanyuan3; Peng, Qian4; Ye, Shanghui2; Li, Qianqian1; Li, Zhen1 |
| 刊名 | SMALL
 |
| 出版日期 | 2016-12-21 |
| 卷号 | 12期号:47页码:6623-6632 |
| 英文摘要 | Silole derivatives, the first reported and famous AIEgens, are a series of Si-containing conjugated rings with the sigma*-pi* conjugation, and this unique electronic structure imparts them high electron affinity and fast electron mobility, but not ideal blue luminogens due to their relatively long conjugation length. By replacing the Si atom with the C one, six new AIEgens without the sigma*-pi* conjugation effect are successfully synthesized based on a tetraphenylcyclopentadiene core. In addition to the skyblue emission (lambda(EL) = 492 nm) with L-max, eta(C,max), and eta(P,max) up to 24 096 cd m(-2), 6.80 cd A(-1), and 4.07 lm W-1, respectively, the careful control of the conjugation degree by changing the linkage mode, results in the blue one (lambda(EL) = 440 nm) with relatively good performance (L-max: 8721 cd m(-2) and eta(C,max): 3.40 cd A(-1)), indicating that the replacement of the Si atom by C one is an alternative design strategy to yield blue even deep-blue AIEgens with good device performance. Meanwhile, their reversible mechanochromic properties are realized with apparent fluorescence changes between deep-blue and green emissive colors, offering them additional promising applications in optoelectronic devices. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/37948]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China 2.Nanjing Univ Posts & Telecommun, KLOEID, IAM, Nanjing 210023, Jiangsu, Peoples R China 3.Hubei Univ, Coll Chem & Chem Engn, Wuhan 430062, Peoples R China 4.Chinese Acad Sci, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ruan, Zhijun,Li, Le,Wang, Can,et al. Tetraphenylcyclopentadiene Derivatives: Aggregation-Induced Emission, Adjustable Luminescence from Green to Blue, Efficient Undoped OLED Performance and Good Mechanochromic Properties[J]. SMALL,2016,12(47):6623-6632. |
| APA | Ruan, Zhijun.,Li, Le.,Wang, Can.,Xie, Yujun.,Hu, Quanyuan.,...&Li, Zhen.(2016).Tetraphenylcyclopentadiene Derivatives: Aggregation-Induced Emission, Adjustable Luminescence from Green to Blue, Efficient Undoped OLED Performance and Good Mechanochromic Properties.SMALL,12(47),6623-6632. |
| MLA | Ruan, Zhijun,et al."Tetraphenylcyclopentadiene Derivatives: Aggregation-Induced Emission, Adjustable Luminescence from Green to Blue, Efficient Undoped OLED Performance and Good Mechanochromic Properties".SMALL 12.47(2016):6623-6632. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。